Electron paramagnetic resonance in trimeric exchange clusters: II. Paramagnetic relaxation

B. S. Tsukerblat; I. G. Botsan; M. I. Belinskii; V. E. Fainzil’berg

doi:10.1080/00268978500103181

Electron paramagnetic resonance in trimeric exchange clusters: II. Paramagnetic relaxation

B. S. Tsukerblat, I. G. Botsan, M. I. Belinskii, V. E. Fainzil’berg

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15 Scopus citations

Abstract

A one-phonon spin-lattice relaxation theory is developed for trimeric exchange clusters. The spin-phonon coupling arises from the modulation of the isotropic exchange interaction by thermal lattice vibrations. Both the mechanisms of relaxation transitions and Van Vleck dipolar broadening give the same order contributions to the observed E.S.R. line widths of trimeric chromium(III) carboxylates.

Original language	English
Pages (from-to)	813-822
Number of pages	10
Journal	Molecular Physics
Volume	54
Issue number	4
DOIs	https://doi.org/10.1080/00268978500103181
State	Published - 1 Jan 1985
Externally published	Yes

ASJC Scopus subject areas

Biophysics
Molecular Biology
Condensed Matter Physics
Physical and Theoretical Chemistry

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10.1080/00268978500103181

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abstract = "A one-phonon spin-lattice relaxation theory is developed for trimeric exchange clusters. The spin-phonon coupling arises from the modulation of the isotropic exchange interaction by thermal lattice vibrations. Both the mechanisms of relaxation transitions and Van Vleck dipolar broadening give the same order contributions to the observed E.S.R. line widths of trimeric chromium(III) carboxylates.",

author = "Tsukerblat, {B. S.} and Botsan, {I. G.} and Belinskii, {M. I.} and Fainzil{\textquoteright}berg, {V. E.}",

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AU - Tsukerblat, B. S.

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AU - Belinskii, M. I.

AU - Fainzil’berg, V. E.

PY - 1985/1/1

Y1 - 1985/1/1

N2 - A one-phonon spin-lattice relaxation theory is developed for trimeric exchange clusters. The spin-phonon coupling arises from the modulation of the isotropic exchange interaction by thermal lattice vibrations. Both the mechanisms of relaxation transitions and Van Vleck dipolar broadening give the same order contributions to the observed E.S.R. line widths of trimeric chromium(III) carboxylates.

AB - A one-phonon spin-lattice relaxation theory is developed for trimeric exchange clusters. The spin-phonon coupling arises from the modulation of the isotropic exchange interaction by thermal lattice vibrations. Both the mechanisms of relaxation transitions and Van Vleck dipolar broadening give the same order contributions to the observed E.S.R. line widths of trimeric chromium(III) carboxylates.

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Electron paramagnetic resonance in trimeric exchange clusters: II. Paramagnetic relaxation

Abstract

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