Abstract
Synchrotron radiation (SR) pulses are used to eject electrons from a gold substrate covered with organized organic thin films (OOTF) in order to investigate their transmission probability through the OOTF as a function of the electron initial kinetic energy. By variation of the SR photon energy within a few eV above the Au-4f binding energy levels we controlled the initial kinetic energy of the substrate electrons. The observed oscillations in the transmission probability for porphyrin-based films as a function of the kinetic energy is argued to be due to effects of band structure above the vacuum level in the well-ordered molecular adsorbate. We also present valence photoemission spectra (PES) of different type OOTF and demonstrate how their coverage of the substrate affects the PES.
Original language | English |
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Pages (from-to) | 445-451 |
Number of pages | 7 |
Journal | European Physical Journal B |
Volume | 8 |
Issue number | 3 |
DOIs | |
State | Published - 1 Jan 1999 |
Externally published | Yes |
Keywords
- 73.20.At Surface states, band structure, electron density of states
- 73.61.Ph Polymers; organic compounds
- 79.60.Dp Adsorbed layers and thin films
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Condensed Matter Physics