Electronic structure and thermodynamic properties of dimeric mixed-valence clusters

M. I. Belinskii; B. S. Tsukerblat; I. G. Botsan; I. S. Belinskaya

doi:10.1007/BF00534573

Electronic structure and thermodynamic properties of dimeric mixed-valence clusters

M. I. Belinskii, B. S. Tsukerblat, I. G. Botsan, I. S. Belinskaya

Research output: Contribution to journal › Article › peer-review

Abstract

A many-electron theory is proposed for exchange and tunneling levels of dimeric mixed-valence clusters. Transition-metal ions are examined, and it is established that the parameters of the Heisenberg and double-exchange interactions depend on the configuration of the d_n-electronic states. Temperature dependences are constructed for the effective magnetic moments and the electronic heat capacity.

Original language	English
Pages (from-to)	141-149
Number of pages	9
Journal	Theoretical and Experimental Chemistry
Volume	23
Issue number	2
DOIs	https://doi.org/10.1007/BF00534573
State	Published - 1 Mar 1987
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1007/BF00534573

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title = "Electronic structure and thermodynamic properties of dimeric mixed-valence clusters",

abstract = "A many-electron theory is proposed for exchange and tunneling levels of dimeric mixed-valence clusters. Transition-metal ions are examined, and it is established that the parameters of the Heisenberg and double-exchange interactions depend on the configuration of the dn-electronic states. Temperature dependences are constructed for the effective magnetic moments and the electronic heat capacity.",

author = "Belinskii, {M. I.} and Tsukerblat, {B. S.} and Botsan, {I. G.} and Belinskaya, {I. S.}",

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AU - Tsukerblat, B. S.

AU - Botsan, I. G.

AU - Belinskaya, I. S.

PY - 1987/3/1

Y1 - 1987/3/1

N2 - A many-electron theory is proposed for exchange and tunneling levels of dimeric mixed-valence clusters. Transition-metal ions are examined, and it is established that the parameters of the Heisenberg and double-exchange interactions depend on the configuration of the dn-electronic states. Temperature dependences are constructed for the effective magnetic moments and the electronic heat capacity.

AB - A many-electron theory is proposed for exchange and tunneling levels of dimeric mixed-valence clusters. Transition-metal ions are examined, and it is established that the parameters of the Heisenberg and double-exchange interactions depend on the configuration of the dn-electronic states. Temperature dependences are constructed for the effective magnetic moments and the electronic heat capacity.

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JO - Theoretical and Experimental Chemistry

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Electronic structure and thermodynamic properties of dimeric mixed-valence clusters

Abstract

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