Electronic structure of organylthiochloroacetylenes and their reactions with O-containing nucleophiles

A. N. Mirskova; S. G. Seredkina; V. A. Shagun; I. D. Kalikhman; V. B. Modonov; N. V. Lutskaya; M. G. Voronkov

doi:10.1007/BF00965368

Electronic structure of organylthiochloroacetylenes and their reactions with O-containing nucleophiles

A. N. Mirskova, S. G. Seredkina, V. A. Shagun, I. D. Kalikhman, V. B. Modonov, N. V. Lutskaya, M. G. Voronkov

Research output: Contribution to journal › Article › peer-review

Abstract

Reactivity of organylthiochloroacetylenes toward O-containing nucleophiles was studied. It was established that phenolate anions attack the acetylenic C atom bound to the Cl atom and alcoholate anions attack the carbon atom bound to the S atom, which corresponds with the data of quantum chemical calculations.

Original language	English
Pages (from-to)	514-518
Number of pages	5
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	37
Issue number	3
DOIs	https://doi.org/10.1007/BF00965368
State	Published - 1 Mar 1988
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1007/BF00965368

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title = "Electronic structure of organylthiochloroacetylenes and their reactions with O-containing nucleophiles",

abstract = "Reactivity of organylthiochloroacetylenes toward O-containing nucleophiles was studied. It was established that phenolate anions attack the acetylenic C atom bound to the Cl atom and alcoholate anions attack the carbon atom bound to the S atom, which corresponds with the data of quantum chemical calculations.",

author = "Mirskova, {A. N.} and Seredkina, {S. G.} and Shagun, {V. A.} and Kalikhman, {I. D.} and Modonov, {V. B.} and Lutskaya, {N. V.} and Voronkov, {M. G.}",

year = "1988",

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volume = "37",

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T1 - Electronic structure of organylthiochloroacetylenes and their reactions with O-containing nucleophiles

AU - Mirskova, A. N.

AU - Seredkina, S. G.

AU - Shagun, V. A.

AU - Kalikhman, I. D.

AU - Modonov, V. B.

AU - Lutskaya, N. V.

AU - Voronkov, M. G.

PY - 1988/3/1

Y1 - 1988/3/1

N2 - Reactivity of organylthiochloroacetylenes toward O-containing nucleophiles was studied. It was established that phenolate anions attack the acetylenic C atom bound to the Cl atom and alcoholate anions attack the carbon atom bound to the S atom, which corresponds with the data of quantum chemical calculations.

AB - Reactivity of organylthiochloroacetylenes toward O-containing nucleophiles was studied. It was established that phenolate anions attack the acetylenic C atom bound to the Cl atom and alcoholate anions attack the carbon atom bound to the S atom, which corresponds with the data of quantum chemical calculations.

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U2 - 10.1007/BF00965368

DO - 10.1007/BF00965368

M3 - Article

AN - SCOPUS:34249975293

SN - 0568-5230

VL - 37

SP - 514

EP - 518

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 3

ER -

Electronic structure of organylthiochloroacetylenes and their reactions with O-containing nucleophiles

Abstract

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