Enabling Iron-Based Highly Effective Electrochemical Water-Splitting and Selective Oxygenation of Organic Substrates through In Situ Surface Modification of Intermetallic Iron Stannide Precatalyst

Biswarup Chakraborty, Rodrigo Beltrán-Suito, J. Niklas Hausmann, Somenath Garai, Matthias Driess, Prashanth W. Menezes

Research output: Contribution to journalArticlepeer-review

85 Scopus citations

Abstract

A strategy to overcome the unsatisfying catalytic performance and the durability of monometallic iron-based materials for the electrochemical oxygen evolution reaction (OER) is provided by heterobimetallic iron–metal systems. Monometallic Fe catalysts show limited performance mostly due to poor conductivity and stability. Here, by taking advantage of the structurally ordered and highly conducting FeSn2 nanostructure, for the first time, an intermetallic iron material is employed as an efficient anode for the alkaline OER, overall water-splitting, and also for selective oxygenation of organic substrates. The electrophoretically deposited FeSn2 on nickel foam (NF) and fluorine-doped tin oxide (FTO) electrodes displays remarkable OER activity and durability with substantially low overpotentials of 197 and 273 mV at 10 mA cm−2, respectively, which outperform most of the benchmarking NiFe-based catalysts. The resulting superior activity is attributed to the in situ generation of α-FeO(OH)@FeSn2 where α-FeO(OH) acts as the active site while FeSn2 remains the conductive core. When the FeSn2 anode is coupled with a Pt cathode for overall alkaline water-splitting, a reduced cell potential (1.53 V) is attained outperforming that of noble metal-based catalysts. FeSn2 is further applied as an anode to produce value-added products through selective oxygenation reactions of organic substrates.

Original languageEnglish
Article number2001377
JournalAdvanced Energy Materials
Volume10
Issue number30
DOIs
StatePublished - 1 Aug 2020
Externally publishedYes

Keywords

  • iron stannides
  • overall water splitting
  • oxygenation
  • oxyhydroxides
  • water oxidation

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • General Materials Science

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