Enantioselective alkynylation of trifluoromethyl ketones catalyzed by chiral Schiff bases

Vasudevan Dhayalan; Ryo Murakami; Masahiko Hayashi

doi:10.14233/ajchem.2013.14943

Enantioselective alkynylation of trifluoromethyl ketones catalyzed by chiral Schiff bases

Vasudevan Dhayalan, Ryo Murakami, Masahiko Hayashi

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Enantioselective alkynylation of trifluoromethyl ketones catalyzed by chiral Schiff bases in the presence of Me2Zn afforded the corresponding trifluoroalkynyl alcohols in up to 66 % ee.

Original language	English
Pages (from-to)	7505-7508
Number of pages	4
Journal	Asian Journal of Chemistry
Volume	25
Issue number	13
DOIs	https://doi.org/10.14233/ajchem.2013.14943
State	Published - 1 Jan 2013
Externally published	Yes

Keywords

Alkynylation
Asymmetric catalysis
Enantioselectivity
Schiff base

ASJC Scopus subject areas

General Chemistry

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10.14233/ajchem.2013.14943

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@article{1ce46405a6ad45febdb65d59c32e85ba,

title = "Enantioselective alkynylation of trifluoromethyl ketones catalyzed by chiral Schiff bases",

abstract = "Enantioselective alkynylation of trifluoromethyl ketones catalyzed by chiral Schiff bases in the presence of Me2Zn afforded the corresponding trifluoroalkynyl alcohols in up to 66 \% ee.",

keywords = "Alkynylation, Asymmetric catalysis, Enantioselectivity, Schiff base",

author = "Vasudevan Dhayalan and Ryo Murakami and Masahiko Hayashi",

year = "2013",

month = jan,

day = "1",

doi = "10.14233/ajchem.2013.14943",

language = "English",

volume = "25",

pages = "7505--7508",

journal = "Asian Journal of Chemistry",

issn = "0970-7077",

publisher = "Asian Publication Corporation",

number = "13",

}

TY - JOUR

T1 - Enantioselective alkynylation of trifluoromethyl ketones catalyzed by chiral Schiff bases

AU - Dhayalan, Vasudevan

AU - Murakami, Ryo

AU - Hayashi, Masahiko

PY - 2013/1/1

Y1 - 2013/1/1

N2 - Enantioselective alkynylation of trifluoromethyl ketones catalyzed by chiral Schiff bases in the presence of Me2Zn afforded the corresponding trifluoroalkynyl alcohols in up to 66 % ee.

AB - Enantioselective alkynylation of trifluoromethyl ketones catalyzed by chiral Schiff bases in the presence of Me2Zn afforded the corresponding trifluoroalkynyl alcohols in up to 66 % ee.

KW - Alkynylation

KW - Asymmetric catalysis

KW - Enantioselectivity

KW - Schiff base

UR - https://www.scopus.com/pages/publications/84880881367

U2 - 10.14233/ajchem.2013.14943

DO - 10.14233/ajchem.2013.14943

M3 - Article

AN - SCOPUS:84880881367

SN - 0970-7077

VL - 25

SP - 7505

EP - 7508

JO - Asian Journal of Chemistry

JF - Asian Journal of Chemistry

IS - 13

ER -

Enantioselective alkynylation of trifluoromethyl ketones catalyzed by chiral Schiff bases

Abstract

Keywords

ASJC Scopus subject areas

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