Energy transfer at 10 and 300 K from chromium(III) to neodymium(III) in mullite glasses and glass-ceramics

W. Nie; Y. Kalisky; G. Boulon; R. Reisfeld

doi:10.1016/0009-2614(89)87044-7

Energy transfer at 10 and 300 K from chromium(III) to neodymium(III) in mullite glasses and glass-ceramics

W. Nie, Y. Kalisky, G. Boulon, R. Reisfeld

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

Energy transfer from Cr³⁺ to Nd³⁺ in mullite glasses and glass-ceramics was investigated at 10 and 300 K. Nd³⁺ and Cr³⁺ emissions were observed using time-resolved laser spectroscopy in the spectral range 640 to 880 nm, and the energy-transfer mechanism was determined. Further information on the dynamic processes was obtained from the decay rates of ²E and ⁴T₂ states of Cr³⁺ and those of the ⁴F_{3 2} level of Nd³⁺ in glasses and glass-ceramics.

Original language	English
Pages (from-to)	282-286
Number of pages	5
Journal	Chemical Physics Letters
Volume	162
Issue number	4-5
DOIs	https://doi.org/10.1016/0009-2614(89)87044-7
State	Published - 20 Oct 1989
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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title = "Energy transfer at 10 and 300 K from chromium(III) to neodymium(III) in mullite glasses and glass-ceramics",

abstract = "Energy transfer from Cr3+ to Nd3+ in mullite glasses and glass-ceramics was investigated at 10 and 300 K. Nd3+ and Cr3+ emissions were observed using time-resolved laser spectroscopy in the spectral range 640 to 880 nm, and the energy-transfer mechanism was determined. Further information on the dynamic processes was obtained from the decay rates of 2E and 4T2 states of Cr3+ and those of the 4F 3 2 level of Nd3+ in glasses and glass-ceramics.",

author = "W. Nie and Y. Kalisky and G. Boulon and R. Reisfeld",

note = "Funding Information: The authors are very grateful to Professor C.K. Jorgensen for fruitful discussions and to Dr. A. Buch and Dr. M. Ish-Shalom for kindly providing us with the glass-ceramic samples. The work was supported by US Army Contract DAJA 45-85-c-0051 and by CNRS and MRES in France.",

year = "1989",

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doi = "10.1016/0009-2614(89)87044-7",

language = "English",

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journal = "Chemical Physics Letters",

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TY - JOUR

T1 - Energy transfer at 10 and 300 K from chromium(III) to neodymium(III) in mullite glasses and glass-ceramics

AU - Nie, W.

AU - Kalisky, Y.

AU - Boulon, G.

AU - Reisfeld, R.

N1 - Funding Information: The authors are very grateful to Professor C.K. Jorgensen for fruitful discussions and to Dr. A. Buch and Dr. M. Ish-Shalom for kindly providing us with the glass-ceramic samples. The work was supported by US Army Contract DAJA 45-85-c-0051 and by CNRS and MRES in France.

PY - 1989/10/20

Y1 - 1989/10/20

N2 - Energy transfer from Cr3+ to Nd3+ in mullite glasses and glass-ceramics was investigated at 10 and 300 K. Nd3+ and Cr3+ emissions were observed using time-resolved laser spectroscopy in the spectral range 640 to 880 nm, and the energy-transfer mechanism was determined. Further information on the dynamic processes was obtained from the decay rates of 2E and 4T2 states of Cr3+ and those of the 4F 3 2 level of Nd3+ in glasses and glass-ceramics.

AB - Energy transfer from Cr3+ to Nd3+ in mullite glasses and glass-ceramics was investigated at 10 and 300 K. Nd3+ and Cr3+ emissions were observed using time-resolved laser spectroscopy in the spectral range 640 to 880 nm, and the energy-transfer mechanism was determined. Further information on the dynamic processes was obtained from the decay rates of 2E and 4T2 states of Cr3+ and those of the 4F 3 2 level of Nd3+ in glasses and glass-ceramics.

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DO - 10.1016/0009-2614(89)87044-7

M3 - Article

AN - SCOPUS:45249127136

SN - 0009-2614

VL - 162

SP - 282

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JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 4-5

ER -

Energy transfer at 10 and 300 K from chromium(III) to neodymium(III) in mullite glasses and glass-ceramics

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