Enthalpy of solution of lithium chloride and of lithium chloride monohydrate in water

Alexander Apelblat; Robert Weintraub; Abraham Tamir

doi:10.1016/0021-9614(84)90161-7

Enthalpy of solution of lithium chloride and of lithium chloride monohydrate in water

Alexander Apelblat
, Robert Weintraub
, Abraham Tamir

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Enthalpies of solution of LiCl and of LiCl · H₂O in water at 298.15 K were measured. Results with different procedures of sample handling are discussed, including the use of the equilibrium between LiCl · H₂O and its aqueous saturated solution as a hygrostat. The molar enthalpies of solution extrapolated to infinite dilution are Δ_solH_m^∞(LiCl, 298.15 K) = -(36653 ± 90) J · mol^-1 and Δ_solH_m^∞(LiCl · H₂O, 298.15 K) = -(18562 ± 54) J · mol^-1. The value for the monohydrate has been calculated by assuming that the excess water in the sample over the theoretical, is present as an aqueous saturated solution.

Original language	English
Pages (from-to)	935-941
Number of pages	7
Journal	The Journal of Chemical Thermodynamics
Volume	16
Issue number	10
DOIs	https://doi.org/10.1016/0021-9614(84)90161-7
State	Published - 1 Jan 1984

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
General Materials Science
Physical and Theoretical Chemistry

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title = "Enthalpy of solution of lithium chloride and of lithium chloride monohydrate in water",

abstract = "Enthalpies of solution of LiCl and of LiCl · H2O in water at 298.15 K were measured. Results with different procedures of sample handling are discussed, including the use of the equilibrium between LiCl · H2O and its aqueous saturated solution as a hygrostat. The molar enthalpies of solution extrapolated to infinite dilution are ΔsolHm∞(LiCl, 298.15 K) = -(36653 ± 90) J · mol-1 and ΔsolHm∞(LiCl · H2O, 298.15 K) = -(18562 ± 54) J · mol-1. The value for the monohydrate has been calculated by assuming that the excess water in the sample over the theoretical, is present as an aqueous saturated solution.",

author = "Alexander Apelblat and Robert Weintraub and Abraham Tamir",

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T1 - Enthalpy of solution of lithium chloride and of lithium chloride monohydrate in water

AU - Apelblat, Alexander

AU - Weintraub, Robert

AU - Tamir, Abraham

PY - 1984/1/1

Y1 - 1984/1/1

N2 - Enthalpies of solution of LiCl and of LiCl · H2O in water at 298.15 K were measured. Results with different procedures of sample handling are discussed, including the use of the equilibrium between LiCl · H2O and its aqueous saturated solution as a hygrostat. The molar enthalpies of solution extrapolated to infinite dilution are ΔsolHm∞(LiCl, 298.15 K) = -(36653 ± 90) J · mol-1 and ΔsolHm∞(LiCl · H2O, 298.15 K) = -(18562 ± 54) J · mol-1. The value for the monohydrate has been calculated by assuming that the excess water in the sample over the theoretical, is present as an aqueous saturated solution.

AB - Enthalpies of solution of LiCl and of LiCl · H2O in water at 298.15 K were measured. Results with different procedures of sample handling are discussed, including the use of the equilibrium between LiCl · H2O and its aqueous saturated solution as a hygrostat. The molar enthalpies of solution extrapolated to infinite dilution are ΔsolHm∞(LiCl, 298.15 K) = -(36653 ± 90) J · mol-1 and ΔsolHm∞(LiCl · H2O, 298.15 K) = -(18562 ± 54) J · mol-1. The value for the monohydrate has been calculated by assuming that the excess water in the sample over the theoretical, is present as an aqueous saturated solution.

UR - https://www.scopus.com/pages/publications/0000608653

U2 - 10.1016/0021-9614(84)90161-7

DO - 10.1016/0021-9614(84)90161-7

M3 - Article

AN - SCOPUS:0000608653

SN - 0021-9614

VL - 16

SP - 935

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JO - The Journal of Chemical Thermodynamics

JF - The Journal of Chemical Thermodynamics

IS - 10

ER -

Enthalpy of solution of lithium chloride and of lithium chloride monohydrate in water

Abstract

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