Enzyme-like catalysis by single chain nanoparticles that use transition metal cofactors

Thao M. Xiong; Edzna S. Garcia; Junfeng Chen; Lingyang Zhu; Ariale J. Alzona; Steven C. Zimmerman

doi:10.1039/d1cc05578j

Enzyme-like catalysis by single chain nanoparticles that use transition metal cofactors

Thao M. Xiong
, Edzna S. Garcia
, Junfeng Chen
, Lingyang Zhu
, Ariale J. Alzona
, Steven C. Zimmerman

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

We report a modular approach in which a noncovalently cross-linked single chain nanoparticle (SCNP) selectively binds catalyst "cofactors"and substrates to increase both the catalytic activity of a Cu-catalyzed alkyne-azide cycloaddition reaction and the Ru-catalyzed cleavage of allylcarbamate groups compared to the free catalysts.

Original language	English
Pages (from-to)	985-988
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	7
DOIs	https://doi.org/10.1039/d1cc05578j
State	Published - 21 Jan 2022
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Catalysis
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/d1cc05578j

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abstract = "We report a modular approach in which a noncovalently cross-linked single chain nanoparticle (SCNP) selectively binds catalyst {"}cofactors{"}and substrates to increase both the catalytic activity of a Cu-catalyzed alkyne-azide cycloaddition reaction and the Ru-catalyzed cleavage of allylcarbamate groups compared to the free catalysts.",

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AU - Xiong, Thao M.

AU - Garcia, Edzna S.

AU - Chen, Junfeng

AU - Zhu, Lingyang

AU - Alzona, Ariale J.

AU - Zimmerman, Steven C.

PY - 2022/1/21

Y1 - 2022/1/21

N2 - We report a modular approach in which a noncovalently cross-linked single chain nanoparticle (SCNP) selectively binds catalyst "cofactors"and substrates to increase both the catalytic activity of a Cu-catalyzed alkyne-azide cycloaddition reaction and the Ru-catalyzed cleavage of allylcarbamate groups compared to the free catalysts.

AB - We report a modular approach in which a noncovalently cross-linked single chain nanoparticle (SCNP) selectively binds catalyst "cofactors"and substrates to increase both the catalytic activity of a Cu-catalyzed alkyne-azide cycloaddition reaction and the Ru-catalyzed cleavage of allylcarbamate groups compared to the free catalysts.

UR - https://www.scopus.com/pages/publications/85123359399

U2 - 10.1039/d1cc05578j

DO - 10.1039/d1cc05578j

M3 - Article

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AN - SCOPUS:85123359399

SN - 1359-7345

VL - 58

SP - 985

EP - 988

JO - Chemical Communications

JF - Chemical Communications

IS - 7

ER -

Enzyme-like catalysis by single chain nanoparticles that use transition metal cofactors

Abstract

ASJC Scopus subject areas

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