Epoxidation of anchovy oils

Jaime Wisniak; Alejandro Cancino; Juan C. Vega

doi:10.1021/i360012a012

Epoxidation of anchovy oils

Jaime Wisniak, Alejandro Cancino, Juan C. Vega

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Anchovy oil has been epoxidized in situ to determine the effect of operating variables on the maximum oxirane oxygen attainable. Variables studied included temperature, catalyst nature and concentration, hydrogen peroxide strength and proportion, and acetic acid proportion. An epoxidized oil with 7.8% epoxy content and iodine value of 1 4.1 can be prepared when operating at 53° to 73° C, using a 33 weight % hydrogen peroxide solution in a proportion of 1.4 moles per mole of ethylenic unsaturation, 15% concentration of styrene-sulfonic resin as catalyst, and acetic acid in the proportion of 0.5 mole per mole of ethylenic unsaturation.

Original language	English
Pages (from-to)	306-311
Number of pages	6
Journal	Industrial & Engineering Chemistry Product Research and Development
Volume	3
Issue number	4
DOIs	https://doi.org/10.1021/i360012a012
State	Published - 1 Dec 1964
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
General Engineering
Industrial and Manufacturing Engineering

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abstract = "Anchovy oil has been epoxidized in situ to determine the effect of operating variables on the maximum oxirane oxygen attainable. Variables studied included temperature, catalyst nature and concentration, hydrogen peroxide strength and proportion, and acetic acid proportion. An epoxidized oil with 7.8% epoxy content and iodine value of 1 4.1 can be prepared when operating at 53° to 73° C, using a 33 weight % hydrogen peroxide solution in a proportion of 1.4 moles per mole of ethylenic unsaturation, 15% concentration of styrene-sulfonic resin as catalyst, and acetic acid in the proportion of 0.5 mole per mole of ethylenic unsaturation.",

author = "Jaime Wisniak and Alejandro Cancino and Vega, {Juan C.}",

year = "1964",

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doi = "10.1021/i360012a012",

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AU - Wisniak, Jaime

AU - Cancino, Alejandro

AU - Vega, Juan C.

PY - 1964/12/1

Y1 - 1964/12/1

N2 - Anchovy oil has been epoxidized in situ to determine the effect of operating variables on the maximum oxirane oxygen attainable. Variables studied included temperature, catalyst nature and concentration, hydrogen peroxide strength and proportion, and acetic acid proportion. An epoxidized oil with 7.8% epoxy content and iodine value of 1 4.1 can be prepared when operating at 53° to 73° C, using a 33 weight % hydrogen peroxide solution in a proportion of 1.4 moles per mole of ethylenic unsaturation, 15% concentration of styrene-sulfonic resin as catalyst, and acetic acid in the proportion of 0.5 mole per mole of ethylenic unsaturation.

AB - Anchovy oil has been epoxidized in situ to determine the effect of operating variables on the maximum oxirane oxygen attainable. Variables studied included temperature, catalyst nature and concentration, hydrogen peroxide strength and proportion, and acetic acid proportion. An epoxidized oil with 7.8% epoxy content and iodine value of 1 4.1 can be prepared when operating at 53° to 73° C, using a 33 weight % hydrogen peroxide solution in a proportion of 1.4 moles per mole of ethylenic unsaturation, 15% concentration of styrene-sulfonic resin as catalyst, and acetic acid in the proportion of 0.5 mole per mole of ethylenic unsaturation.

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JF - Industrial & Engineering Chemistry Product Research and Development

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Epoxidation of anchovy oils

Abstract

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