EPR-study of reversible oxygenation process of coordination compounds of cobalt(II) with S-substituted N1,N4-di(salicylidene)-isothiosemicarbazides

N. V. Gerbeleu; M. D. Revenko; V. G. Rusu; A. T. Shames

doi:10.1007/BF00534587

EPR-study of reversible oxygenation process of coordination compounds of cobalt(II) with S-substituted N¹,N⁴-di(salicylidene)-isothiosemicarbazides

N. V. Gerbeleu, M. D. Revenko, V. G. Rusu, A. T. Shames

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The reaction between molecular oxygen and coordination compounds of cobalt(II) with S-substituted N¹,N⁴-di(salicylidene)isothiosemicarbazides in dimethyl sulfoxide solution was studied by the EPR method. It was found that paramagnetic monomeric adducts and diamagnetic μ-peroxo-dimers are formed. The spin-Hamiltonian parameters of the EPR spectra of the initial cobalt complexes, as well as of the paramagnetic adducts were determined. The nature of the Co-O₂ bond is discussed.

Original language	English
Pages (from-to)	216-219
Number of pages	4
Journal	Theoretical and Experimental Chemistry
Volume	23
Issue number	2
DOIs	https://doi.org/10.1007/BF00534587
State	Published - 1 Mar 1987
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1007/BF00534587

Cite this

@article{fb721121ab9b4d4680fdcf3758ebd440,

title = "EPR-study of reversible oxygenation process of coordination compounds of cobalt(II) with S-substituted N1,N4-di(salicylidene)-isothiosemicarbazides",

abstract = "The reaction between molecular oxygen and coordination compounds of cobalt(II) with S-substituted N1,N4-di(salicylidene)isothiosemicarbazides in dimethyl sulfoxide solution was studied by the EPR method. It was found that paramagnetic monomeric adducts and diamagnetic μ-peroxo-dimers are formed. The spin-Hamiltonian parameters of the EPR spectra of the initial cobalt complexes, as well as of the paramagnetic adducts were determined. The nature of the Co-O2 bond is discussed.",

author = "Gerbeleu, {N. V.} and Revenko, {M. D.} and Rusu, {V. G.} and Shames, {A. T.}",

year = "1987",

month = mar,

day = "1",

doi = "10.1007/BF00534587",

language = "English",

volume = "23",

pages = "216--219",

journal = "Theoretical and Experimental Chemistry",

issn = "0040-5760",

publisher = "Springer New York",

number = "2",

}

TY - JOUR

T1 - EPR-study of reversible oxygenation process of coordination compounds of cobalt(II) with S-substituted N1,N4-di(salicylidene)-isothiosemicarbazides

AU - Gerbeleu, N. V.

AU - Revenko, M. D.

AU - Rusu, V. G.

AU - Shames, A. T.

PY - 1987/3/1

Y1 - 1987/3/1

N2 - The reaction between molecular oxygen and coordination compounds of cobalt(II) with S-substituted N1,N4-di(salicylidene)isothiosemicarbazides in dimethyl sulfoxide solution was studied by the EPR method. It was found that paramagnetic monomeric adducts and diamagnetic μ-peroxo-dimers are formed. The spin-Hamiltonian parameters of the EPR spectra of the initial cobalt complexes, as well as of the paramagnetic adducts were determined. The nature of the Co-O2 bond is discussed.

AB - The reaction between molecular oxygen and coordination compounds of cobalt(II) with S-substituted N1,N4-di(salicylidene)isothiosemicarbazides in dimethyl sulfoxide solution was studied by the EPR method. It was found that paramagnetic monomeric adducts and diamagnetic μ-peroxo-dimers are formed. The spin-Hamiltonian parameters of the EPR spectra of the initial cobalt complexes, as well as of the paramagnetic adducts were determined. The nature of the Co-O2 bond is discussed.

UR - http://www.scopus.com/inward/record.url?scp=34250108185&partnerID=8YFLogxK

U2 - 10.1007/BF00534587

DO - 10.1007/BF00534587

M3 - Article

AN - SCOPUS:34250108185

SN - 0040-5760

VL - 23

SP - 216

EP - 219

JO - Theoretical and Experimental Chemistry

JF - Theoretical and Experimental Chemistry

IS - 2

ER -

EPR-study of reversible oxygenation process of coordination compounds of cobalt(II) with S-substituted N¹,N⁴-di(salicylidene)-isothiosemicarbazides

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this