Equilibrium between neutral hexacoordinate silicon complexes and ionic pentacoordinate siliconium salts through fast dissociation-recombination of the Si-Cl bond

V. Kingston, B. Gostevskii, I. Kalikhman, D. Kost

Research output: Contribution to journalArticlepeer-review

40 Scopus citations

Abstract

Equilibrium between neutral hexacoordinate silicon complexes and ionic siliconium chlorides, which is highly temperature, solvent, counterion, ligand and substituent dependent, was observed by low temperature 29Si NMR and confirmed by crystal analysis.

Original languageEnglish
Pages (from-to)1272-1273
Number of pages2
JournalChemical Communications
Issue number14
DOIs
StatePublished - 21 Jul 2001

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry (all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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