Evidence for adduct formation between ONOO- and CO2 from high-pressure pulse radiolysis

Sara Goldstern; Dan Meyerstein; Rudi Van Eldik; Gidon Czapski

doi:10.1021/jp002093c

Evidence for adduct formation between ONOO^- and CO₂ from high-pressure pulse radiolysis

Sara Goldstern, Dan Meyerstein, Rudi Van Eldik, Gidon Czapski

Department of Chemistry

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10 Scopus citations

Abstract

The activation volume for the reaction of CO₂ with ONOO^- has been determined to be -22 cm³ mol^-1 using the high-pressure pulse radiolysis technique. The significant negative volume of activation provides conclusive evidence for a short-lived cyclo-adduct formation between ONOO^- and CO₂.

Original language	English
Pages (from-to)	9712-9714
Number of pages	3
Journal	Journal of Physical Chemistry A
Volume	104
Issue number	43
DOIs	https://doi.org/10.1021/jp002093c
State	Published - 2 Nov 2000

ASJC Scopus subject areas

Physical and Theoretical Chemistry

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@article{828f6e7b8eb9474ca5d7e56d569dafdc,

title = "Evidence for adduct formation between ONOO- and CO2 from high-pressure pulse radiolysis",

abstract = "The activation volume for the reaction of CO2 with ONOO- has been determined to be -22 cm3 mol-1 using the high-pressure pulse radiolysis technique. The significant negative volume of activation provides conclusive evidence for a short-lived cyclo-adduct formation between ONOO- and CO2.",

author = "Sara Goldstern and Dan Meyerstein and {Van Eldik}, Rudi and Gidon Czapski",

year = "2000",

month = nov,

day = "2",

doi = "10.1021/jp002093c",

language = "English",

volume = "104",

pages = "9712--9714",

journal = "Journal of Physical Chemistry A",

issn = "1089-5639",

publisher = "American Chemical Society",

number = "43",

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TY - JOUR

T1 - Evidence for adduct formation between ONOO- and CO2 from high-pressure pulse radiolysis

AU - Goldstern, Sara

AU - Meyerstein, Dan

AU - Van Eldik, Rudi

AU - Czapski, Gidon

PY - 2000/11/2

Y1 - 2000/11/2

N2 - The activation volume for the reaction of CO2 with ONOO- has been determined to be -22 cm3 mol-1 using the high-pressure pulse radiolysis technique. The significant negative volume of activation provides conclusive evidence for a short-lived cyclo-adduct formation between ONOO- and CO2.

AB - The activation volume for the reaction of CO2 with ONOO- has been determined to be -22 cm3 mol-1 using the high-pressure pulse radiolysis technique. The significant negative volume of activation provides conclusive evidence for a short-lived cyclo-adduct formation between ONOO- and CO2.

UR - http://www.scopus.com/inward/record.url?scp=0034322716&partnerID=8YFLogxK

U2 - 10.1021/jp002093c

DO - 10.1021/jp002093c

M3 - Article

AN - SCOPUS:0034322716

SN - 1089-5639

VL - 104

SP - 9712

EP - 9714

JO - Journal of Physical Chemistry A

JF - Journal of Physical Chemistry A

IS - 43

ER -

Evidence for adduct formation between ONOO^- and CO₂ from high-pressure pulse radiolysis

Abstract

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