Exchange reactions of bis(triethylgermyl)mercury with mercury derivatives of acetylacetone, diethyl malonate, and related compounds

L. I. Belousova, O. A. Kruglaya, V. V. Neretin, I. D. Kalikhman, N. A. Ivanova, A. A. Tatarinova, N. S. Vyazankin

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Abstract

1. Radical exchange between bis(triethylgermyl)mercury and mercury acetylacetonate is accompanied by demercuration and forms 2-(triethylgermoxy)pent-2-en-4-one, the cis isomer of which shows 1,5-migration of the Et3Ge group between the two oxygen atoms of the acetylacetonate moiety. 2. Mercuribis(diethyl malonate), mercuribis(ethyl cyanoacetate), mercuribis(malononitrile), and mercuribis(acetonitrile) easily undergo exchange reactions with bis(triethylgermyl)mercury; these are accompanied by demercuration.

Original languageEnglish
Pages (from-to)1915-1920
Number of pages6
JournalBulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume26
Issue number9
DOIs
StatePublished - 1 Sep 1977
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry (all)

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