Exchange reactions of bis(triethylgermyl)mercury with mercury derivatives of acetylacetone, diethyl malonate, and related compounds

L. I. Belousova; O. A. Kruglaya; V. V. Neretin; I. D. Kalikhman; N. A. Ivanova; A. A. Tatarinova; N. S. Vyazankin

doi:10.1007/BF00924389

Exchange reactions of bis(triethylgermyl)mercury with mercury derivatives of acetylacetone, diethyl malonate, and related compounds

L. I. Belousova, O. A. Kruglaya, V. V. Neretin, I. D. Kalikhman, N. A. Ivanova, A. A. Tatarinova, N. S. Vyazankin

Research output: Contribution to journal › Article › peer-review

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Abstract

1. Radical exchange between bis(triethylgermyl)mercury and mercury acetylacetonate is accompanied by demercuration and forms 2-(triethylgermoxy)pent-2-en-4-one, the cis isomer of which shows 1,5-migration of the Et₃Ge group between the two oxygen atoms of the acetylacetonate moiety. 2. Mercuribis(diethyl malonate), mercuribis(ethyl cyanoacetate), mercuribis(malononitrile), and mercuribis(acetonitrile) easily undergo exchange reactions with bis(triethylgermyl)mercury; these are accompanied by demercuration.

Original language	English
Pages (from-to)	1915-1920
Number of pages	6
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	26
Issue number	9
DOIs	https://doi.org/10.1007/BF00924389
State	Published - 1 Sep 1977
Externally published	Yes

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General Chemistry

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Belousova, L. I., Kruglaya, O. A., Neretin, V. V., Kalikhman, I. D., Ivanova, N. A., Tatarinova, A. A., & Vyazankin, N. S. (1977). Exchange reactions of bis(triethylgermyl)mercury with mercury derivatives of acetylacetone, diethyl malonate, and related compounds. Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 26(9), 1915-1920. https://doi.org/10.1007/BF00924389

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title = "Exchange reactions of bis(triethylgermyl)mercury with mercury derivatives of acetylacetone, diethyl malonate, and related compounds",

abstract = "1. Radical exchange between bis(triethylgermyl)mercury and mercury acetylacetonate is accompanied by demercuration and forms 2-(triethylgermoxy)pent-2-en-4-one, the cis isomer of which shows 1,5-migration of the Et3Ge group between the two oxygen atoms of the acetylacetonate moiety. 2. Mercuribis(diethyl malonate), mercuribis(ethyl cyanoacetate), mercuribis(malononitrile), and mercuribis(acetonitrile) easily undergo exchange reactions with bis(triethylgermyl)mercury; these are accompanied by demercuration.",

author = "Belousova, {L. I.} and Kruglaya, {O. A.} and Neretin, {V. V.} and Kalikhman, {I. D.} and Ivanova, {N. A.} and Tatarinova, {A. A.} and Vyazankin, {N. S.}",

year = "1977",

month = sep,

day = "1",

doi = "10.1007/BF00924389",

language = "English",

volume = "26",

pages = "1915--1920",

journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

issn = "0568-5230",

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number = "9",

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Belousova, LI, Kruglaya, OA, Neretin, VV, Kalikhman, ID, Ivanova, NA, Tatarinova, AA & Vyazankin, NS 1977, 'Exchange reactions of bis(triethylgermyl)mercury with mercury derivatives of acetylacetone, diethyl malonate, and related compounds', Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, vol. 26, no. 9, pp. 1915-1920. https://doi.org/10.1007/BF00924389

Exchange reactions of bis(triethylgermyl)mercury with mercury derivatives of acetylacetone, diethyl malonate, and related compounds. / Belousova, L. I.; Kruglaya, O. A.; Neretin, V. V. et al.
In: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, Vol. 26, No. 9, 01.09.1977, p. 1915-1920.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Exchange reactions of bis(triethylgermyl)mercury with mercury derivatives of acetylacetone, diethyl malonate, and related compounds

AU - Belousova, L. I.

AU - Kruglaya, O. A.

AU - Neretin, V. V.

AU - Kalikhman, I. D.

AU - Ivanova, N. A.

AU - Tatarinova, A. A.

AU - Vyazankin, N. S.

PY - 1977/9/1

Y1 - 1977/9/1

N2 - 1. Radical exchange between bis(triethylgermyl)mercury and mercury acetylacetonate is accompanied by demercuration and forms 2-(triethylgermoxy)pent-2-en-4-one, the cis isomer of which shows 1,5-migration of the Et3Ge group between the two oxygen atoms of the acetylacetonate moiety. 2. Mercuribis(diethyl malonate), mercuribis(ethyl cyanoacetate), mercuribis(malononitrile), and mercuribis(acetonitrile) easily undergo exchange reactions with bis(triethylgermyl)mercury; these are accompanied by demercuration.

AB - 1. Radical exchange between bis(triethylgermyl)mercury and mercury acetylacetonate is accompanied by demercuration and forms 2-(triethylgermoxy)pent-2-en-4-one, the cis isomer of which shows 1,5-migration of the Et3Ge group between the two oxygen atoms of the acetylacetonate moiety. 2. Mercuribis(diethyl malonate), mercuribis(ethyl cyanoacetate), mercuribis(malononitrile), and mercuribis(acetonitrile) easily undergo exchange reactions with bis(triethylgermyl)mercury; these are accompanied by demercuration.

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DO - 10.1007/BF00924389

M3 - Article

AN - SCOPUS:34250289292

SN - 0568-5230

VL - 26

SP - 1915

EP - 1920

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

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Exchange reactions of bis(triethylgermyl)mercury with mercury derivatives of acetylacetone, diethyl malonate, and related compounds

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