@article{9b1c12cd47314dd58c1440324afb5fa2,
title = "Expanding the hierarchy of metal-oxide building blocks from fragments via clusters to networks: A∞2[({Mo17(NO) 2}3{MoV2}3{Fe III}6)(FeII1.5)]-type layer compound",
abstract = "A planar network consisting of {Mo17(NO)2} 3{Mo2V}3{Fe6 III} cluster entities that are interlinked to layers via {Fe II(H2O)4}2+ groups is formed stepwise from building units. The corresponding mixed-valence compound exhibits a variety of different formal oxidation states: (MoNO)3+, Mo V, MoVI, FeII, and FeIII. This compound also represents an extension of building-block hierarchy from the molecular level to extended networks.",
keywords = "Building block, Extended structure, Iron, Magnetochemistry, Mixed-valence, Molybdenum, Polyoxometalates",
author = "Achim M{\"u}ller and Sergei Talismanov and Paul K{\"o}gerler and Hartmut B{\"o}gge and Marc Schmidtmann and Boris Tsukerblat",
note = "Funding Information: We thank E. Krickemeyer and Dr. S.K. Das for assistance in the synthesis and Prof. A.X. Trautwein and Dr. V. Sch{\"u}nemann for their collaboration, i.e. for the measurement of the M{\"o}ssbauer spectrum, the European Union (MRTN-CT-2003-504880), the German-Israeli Foundation for Scientific Research and Development (G-775-19.10/2003), and the Deutsche Forschungsgemeinschaft as well as the Fonds der Chemischen Industrie for financial support.",
year = "2005",
month = sep,
day = "1",
doi = "10.1007/s10876-005-0008-y",
language = "English",
volume = "16",
pages = "391--396",
journal = "Journal of Cluster Science",
issn = "1040-7278",
publisher = "Springer New York",
number = "3",
}