Expanding the hierarchy of metal-oxide building blocks from fragments via clusters to networks: A∞2[({Mo17(NO) 2}3{MoV2}3{Fe III}6)(FeII1.5)]-type layer compound

Achim Müller; Sergei Talismanov; Paul Kögerler; Hartmut Bögge; Marc Schmidtmann; Boris Tsukerblat

doi:10.1007/s10876-005-0008-y

Expanding the hierarchy of metal-oxide building blocks from fragments via clusters to networks: A_∞²[({Mo₁₇(NO) ₂}₃{Mo^V₂}₃{Fe ^III}₆)(Fe^II_1.5)]-type layer compound

Achim Müller, Sergei Talismanov, Paul Kögerler, Hartmut Bögge, Marc Schmidtmann, Boris Tsukerblat

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A planar network consisting of {Mo₁₇(NO)₂} ₃{Mo₂^V}₃{Fe₆ ^III} cluster entities that are interlinked to layers via {Fe ^II(H₂O)₄}²⁺ groups is formed stepwise from building units. The corresponding mixed-valence compound exhibits a variety of different formal oxidation states: (MoNO)³⁺, Mo ^V, Mo^VI, Fe^II, and Fe^III. This compound also represents an extension of building-block hierarchy from the molecular level to extended networks.

Original language	English
Pages (from-to)	391-396
Number of pages	6
Journal	Journal of Cluster Science
Volume	16
Issue number	3
DOIs	https://doi.org/10.1007/s10876-005-0008-y
State	Published - 1 Sep 2005

Keywords

Building block
Extended structure
Iron
Magnetochemistry
Mixed-valence
Molybdenum
Polyoxometalates

ASJC Scopus subject areas

Biochemistry
General Chemistry
General Materials Science
Condensed Matter Physics

Access to Document

10.1007/s10876-005-0008-y

Cite this

@article{9b1c12cd47314dd58c1440324afb5fa2,

title = "Expanding the hierarchy of metal-oxide building blocks from fragments via clusters to networks: A∞2[({Mo17(NO) 2}3{MoV2}3{Fe III}6)(FeII1.5)]-type layer compound",

abstract = "A planar network consisting of {Mo17(NO)2} 3{Mo2V}3{Fe6 III} cluster entities that are interlinked to layers via {Fe II(H2O)4}2+ groups is formed stepwise from building units. The corresponding mixed-valence compound exhibits a variety of different formal oxidation states: (MoNO)3+, Mo V, MoVI, FeII, and FeIII. This compound also represents an extension of building-block hierarchy from the molecular level to extended networks.",

keywords = "Building block, Extended structure, Iron, Magnetochemistry, Mixed-valence, Molybdenum, Polyoxometalates",

author = "Achim M{\"u}ller and Sergei Talismanov and Paul K{\"o}gerler and Hartmut B{\"o}gge and Marc Schmidtmann and Boris Tsukerblat",

note = "Funding Information: We thank E. Krickemeyer and Dr. S.K. Das for assistance in the synthesis and Prof. A.X. Trautwein and Dr. V. Sch{\"u}nemann for their collaboration, i.e. for the measurement of the M{\"o}ssbauer spectrum, the European Union (MRTN-CT-2003-504880), the German-Israeli Foundation for Scientific Research and Development (G-775-19.10/2003), and the Deutsche Forschungsgemeinschaft as well as the Fonds der Chemischen Industrie for financial support.",

year = "2005",

month = sep,

day = "1",

doi = "10.1007/s10876-005-0008-y",

language = "English",

volume = "16",

pages = "391--396",

journal = "Journal of Cluster Science",

issn = "1040-7278",

publisher = "Springer New York",

number = "3",

}

TY - JOUR

T1 - Expanding the hierarchy of metal-oxide building blocks from fragments via clusters to networks

T2 - A∞2[({Mo17(NO) 2}3{MoV2}3{Fe III}6)(FeII1.5)]-type layer compound

AU - Müller, Achim

AU - Talismanov, Sergei

AU - Kögerler, Paul

AU - Bögge, Hartmut

AU - Schmidtmann, Marc

AU - Tsukerblat, Boris

N1 - Funding Information: We thank E. Krickemeyer and Dr. S.K. Das for assistance in the synthesis and Prof. A.X. Trautwein and Dr. V. Schünemann for their collaboration, i.e. for the measurement of the Mössbauer spectrum, the European Union (MRTN-CT-2003-504880), the German-Israeli Foundation for Scientific Research and Development (G-775-19.10/2003), and the Deutsche Forschungsgemeinschaft as well as the Fonds der Chemischen Industrie for financial support.

PY - 2005/9/1

Y1 - 2005/9/1

N2 - A planar network consisting of {Mo17(NO)2} 3{Mo2V}3{Fe6 III} cluster entities that are interlinked to layers via {Fe II(H2O)4}2+ groups is formed stepwise from building units. The corresponding mixed-valence compound exhibits a variety of different formal oxidation states: (MoNO)3+, Mo V, MoVI, FeII, and FeIII. This compound also represents an extension of building-block hierarchy from the molecular level to extended networks.

AB - A planar network consisting of {Mo17(NO)2} 3{Mo2V}3{Fe6 III} cluster entities that are interlinked to layers via {Fe II(H2O)4}2+ groups is formed stepwise from building units. The corresponding mixed-valence compound exhibits a variety of different formal oxidation states: (MoNO)3+, Mo V, MoVI, FeII, and FeIII. This compound also represents an extension of building-block hierarchy from the molecular level to extended networks.

KW - Building block

KW - Extended structure

KW - Iron

KW - Magnetochemistry

KW - Mixed-valence

KW - Molybdenum

KW - Polyoxometalates

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U2 - 10.1007/s10876-005-0008-y

DO - 10.1007/s10876-005-0008-y

M3 - Article

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SP - 391

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JO - Journal of Cluster Science

JF - Journal of Cluster Science

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