Expanding the hierarchy of metal-oxide building blocks from fragments via clusters to networks: A2[({Mo17(NO) 2}3{MoV2}3{Fe III}6)(FeII1.5)]-type layer compound

Achim Müller, Sergei Talismanov, Paul Kögerler, Hartmut Bögge, Marc Schmidtmann, Boris Tsukerblat

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

A planar network consisting of {Mo17(NO)2} 3{Mo2V}3{Fe6 III} cluster entities that are interlinked to layers via {Fe II(H2O)4}2+ groups is formed stepwise from building units. The corresponding mixed-valence compound exhibits a variety of different formal oxidation states: (MoNO)3+, Mo V, MoVI, FeII, and FeIII. This compound also represents an extension of building-block hierarchy from the molecular level to extended networks.

Original languageEnglish
Pages (from-to)391-396
Number of pages6
JournalJournal of Cluster Science
Volume16
Issue number3
DOIs
StatePublished - 1 Sep 2005

Keywords

  • Building block
  • Extended structure
  • Iron
  • Magnetochemistry
  • Mixed-valence
  • Molybdenum
  • Polyoxometalates

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