Extraction of zinc and copper nitrates by methyl diphenyl phosphate

Alexander Apelblat; Reuben Levin

doi:10.1039/DT9740001476

Extraction of zinc and copper nitrates by methyl diphenyl phosphate

Alexander Apelblat, Reuben Levin

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Abstract

Extraction equilibria in the zinc nitrate-water-methyl diphenyl phosphate (MePh₂PO₄) and copper nitrate-water-MePh₂PO₄ systems have been investigated. The data found are consistent with formation of partially dissociated [Zn(NO₃)₂(H₂O)₂(MePh ₂PO₄)₃] and [Cu(NO₃)₂(H₂O)₃(MePh ₂PO₄)₃] complexes. In the case of zinc, the equilibrium constant for complex formation K = (3.6 ± 0.7) × 10^-6 (mol kg^-1 MePh₂PO₄)^-1.

Original language	English
Pages (from-to)	1476-1478
Number of pages	3
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	14
DOIs	https://doi.org/10.1039/DT9740001476
State	Published - 1 Dec 1974
Externally published	Yes

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General Chemistry

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title = "Extraction of zinc and copper nitrates by methyl diphenyl phosphate",

abstract = "Extraction equilibria in the zinc nitrate-water-methyl diphenyl phosphate (MePh2PO4) and copper nitrate-water-MePh2PO4 systems have been investigated. The data found are consistent with formation of partially dissociated [Zn(NO3)2(H2O)2(MePh 2PO4)3] and [Cu(NO3)2(H2O)3(MePh 2PO4)3] complexes. In the case of zinc, the equilibrium constant for complex formation K = (3.6 ± 0.7) × 10-6 (mol kg-1 MePh2PO4)-1.",

author = "Alexander Apelblat and Reuben Levin",

year = "1974",

month = dec,

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doi = "10.1039/DT9740001476",

language = "English",

pages = "1476--1478",

journal = "Journal of the Chemical Society. Dalton Transactions",

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T1 - Extraction of zinc and copper nitrates by methyl diphenyl phosphate

AU - Apelblat, Alexander

AU - Levin, Reuben

PY - 1974/12/1

Y1 - 1974/12/1

N2 - Extraction equilibria in the zinc nitrate-water-methyl diphenyl phosphate (MePh2PO4) and copper nitrate-water-MePh2PO4 systems have been investigated. The data found are consistent with formation of partially dissociated [Zn(NO3)2(H2O)2(MePh 2PO4)3] and [Cu(NO3)2(H2O)3(MePh 2PO4)3] complexes. In the case of zinc, the equilibrium constant for complex formation K = (3.6 ± 0.7) × 10-6 (mol kg-1 MePh2PO4)-1.

AB - Extraction equilibria in the zinc nitrate-water-methyl diphenyl phosphate (MePh2PO4) and copper nitrate-water-MePh2PO4 systems have been investigated. The data found are consistent with formation of partially dissociated [Zn(NO3)2(H2O)2(MePh 2PO4)3] and [Cu(NO3)2(H2O)3(MePh 2PO4)3] complexes. In the case of zinc, the equilibrium constant for complex formation K = (3.6 ± 0.7) × 10-6 (mol kg-1 MePh2PO4)-1.

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DO - 10.1039/DT9740001476

M3 - Article

AN - SCOPUS:37049114690

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JO - Journal of the Chemical Society. Dalton Transactions

JF - Journal of the Chemical Society. Dalton Transactions

IS - 14

ER -

Extraction of zinc and copper nitrates by methyl diphenyl phosphate

Abstract

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