Extraction of zinc and copper nitrates by methyl diphenyl phosphate

Alexander Apelblat, Reuben Levin

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1 Scopus citations

Abstract

Extraction equilibria in the zinc nitrate-water-methyl diphenyl phosphate (MePh2PO4) and copper nitrate-water-MePh2PO4 systems have been investigated. The data found are consistent with formation of partially dissociated [Zn(NO3)2(H2O)2(MePh 2PO4)3] and [Cu(NO3)2(H2O)3(MePh 2PO4)3] complexes. In the case of zinc, the equilibrium constant for complex formation K = (3.6 ± 0.7) × 10-6 (mol kg-1 MePh2PO4)-1.

Original languageEnglish
Pages (from-to)1476-1478
Number of pages3
JournalJournal of the Chemical Society. Dalton Transactions
Issue number14
DOIs
StatePublished - 1 Dec 1974
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry (all)

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