Far-infrared spectrum of HCl dimers

B. Katz; A. Ron; O. Schnepp

doi:10.1063/1.1701794

Far-infrared spectrum of HCl dimers

B. Katz, A. Ron, O. Schnepp

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

HCl absorptions have been observed in the wavelength region 150-250 cm ^-1 in solid rare-gas solutions. From the dependence of the absorption intensity on sample preparations it is concluded that these spectra are due to polymers formed on condensation. In solid xenon, the isotopic pattern of the spectrum requires the assignment to cyclic dimer molecules of HCl. In the other solid solutions additional bands appear in this region, which have not been definitely assigned. The hydrogen-bond stretching force constant has been calculated from the measurements.

Original language	English
Pages (from-to)	5303-5306
Number of pages	4
Journal	Journal of Chemical Physics
Volume	47
Issue number	12
DOIs	https://doi.org/10.1063/1.1701794
State	Published - 1 Jan 1967
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

Access to Document

10.1063/1.1701794

Cite this

@article{7308e9ca1ac3498e8e1043ad7a38c08c,

title = "Far-infrared spectrum of HCl dimers",

abstract = "HCl absorptions have been observed in the wavelength region 150-250 cm -1 in solid rare-gas solutions. From the dependence of the absorption intensity on sample preparations it is concluded that these spectra are due to polymers formed on condensation. In solid xenon, the isotopic pattern of the spectrum requires the assignment to cyclic dimer molecules of HCl. In the other solid solutions additional bands appear in this region, which have not been definitely assigned. The hydrogen-bond stretching force constant has been calculated from the measurements.",

author = "B. Katz and A. Ron and O. Schnepp",

year = "1967",

month = jan,

day = "1",

doi = "10.1063/1.1701794",

language = "English",

volume = "47",

pages = "5303--5306",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "12",

}

TY - JOUR

T1 - Far-infrared spectrum of HCl dimers

AU - Katz, B.

AU - Ron, A.

AU - Schnepp, O.

PY - 1967/1/1

Y1 - 1967/1/1

N2 - HCl absorptions have been observed in the wavelength region 150-250 cm -1 in solid rare-gas solutions. From the dependence of the absorption intensity on sample preparations it is concluded that these spectra are due to polymers formed on condensation. In solid xenon, the isotopic pattern of the spectrum requires the assignment to cyclic dimer molecules of HCl. In the other solid solutions additional bands appear in this region, which have not been definitely assigned. The hydrogen-bond stretching force constant has been calculated from the measurements.

AB - HCl absorptions have been observed in the wavelength region 150-250 cm -1 in solid rare-gas solutions. From the dependence of the absorption intensity on sample preparations it is concluded that these spectra are due to polymers formed on condensation. In solid xenon, the isotopic pattern of the spectrum requires the assignment to cyclic dimer molecules of HCl. In the other solid solutions additional bands appear in this region, which have not been definitely assigned. The hydrogen-bond stretching force constant has been calculated from the measurements.

UR - http://www.scopus.com/inward/record.url?scp=0004816739&partnerID=8YFLogxK

U2 - 10.1063/1.1701794

DO - 10.1063/1.1701794

M3 - Article

AN - SCOPUS:0004816739

SN - 0021-9606

VL - 47

SP - 5303

EP - 5306

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 12

ER -

Far-infrared spectrum of HCl dimers

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this