Features op the protonation of N-vinylpyrroles

M. V. Sigalov; E. Yu Schmidt; B. A. Trofimov

doi:10.1007/BF00956371

Features op the protonation of N-vinylpyrroles

M. V. Sigalov, E. Yu Schmidt, B. A. Trofimov

Research output: Contribution to journal › Article › peer-review

Abstract

The protonation of N-vinylpyrroles by fluorosulfonic and trifluoroacetic acids occurs at the α-carbon atom of the pyrrole ring. Dimerization of the cation formed takes place in CF₃CO₂H. The rate of this process is much higher for the 2-phenyl derivative than for the 2-alkylvinylpyrrole derivative.

Original language	English
Pages (from-to)	1060-1062
Number of pages	3
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	36
Issue number	5
DOIs	https://doi.org/10.1007/BF00956371
State	Published - 1 Jan 1987
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1007/BF00956371

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title = "Features op the protonation of N-vinylpyrroles",

abstract = "The protonation of N-vinylpyrroles by fluorosulfonic and trifluoroacetic acids occurs at the α-carbon atom of the pyrrole ring. Dimerization of the cation formed takes place in CF3CO2H. The rate of this process is much higher for the 2-phenyl derivative than for the 2-alkylvinylpyrrole derivative.",

author = "Sigalov, {M. V.} and Schmidt, {E. Yu} and Trofimov, {B. A.}",

year = "1987",

month = jan,

day = "1",

doi = "10.1007/BF00956371",

language = "English",

volume = "36",

pages = "1060--1062",

journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

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T1 - Features op the protonation of N-vinylpyrroles

AU - Sigalov, M. V.

AU - Schmidt, E. Yu

AU - Trofimov, B. A.

PY - 1987/1/1

Y1 - 1987/1/1

N2 - The protonation of N-vinylpyrroles by fluorosulfonic and trifluoroacetic acids occurs at the α-carbon atom of the pyrrole ring. Dimerization of the cation formed takes place in CF3CO2H. The rate of this process is much higher for the 2-phenyl derivative than for the 2-alkylvinylpyrrole derivative.

AB - The protonation of N-vinylpyrroles by fluorosulfonic and trifluoroacetic acids occurs at the α-carbon atom of the pyrrole ring. Dimerization of the cation formed takes place in CF3CO2H. The rate of this process is much higher for the 2-phenyl derivative than for the 2-alkylvinylpyrrole derivative.

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U2 - 10.1007/BF00956371

DO - 10.1007/BF00956371

M3 - Article

AN - SCOPUS:34250103303

SN - 0568-5230

VL - 36

SP - 1060

EP - 1062

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 5

ER -

Features op the protonation of N-vinylpyrroles

Abstract

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