Field Scale Mobility and Transport Manipulation of Carbon-Supported Nanoscale Zerovalent Iron in Fractured Media

Meirav Cohen, Noam Weisbrod

Research output: Contribution to journalArticlepeer-review

29 Scopus citations

Abstract

In field applications, mostly in porous media, transport of stabilized nano zerovalent iron particles (nZVI) has never exceeded a few meters in range. In the present study, the transport of Carbo-Iron Colloids (CIC), a composite material of activated carbon as a carrier for nZVI stabilized by carboxymethyl cellulose (CMC), was tested under field conditions. The field site lies within a fractured chalk aquitard characterized by moderately saline (∼13 mS) groundwater. A forced gradient tracer test was conducted where one borehole was pumped at a rate of 8 L/min and CMC-stabilized CIC was introduced at an injection borehole 47 m up-gradient. Two CIC-CMC field applications were conducted: one used high 100% wt CMC (40 g/L) and a second used lower 9% wt loading (∼2.7 g/L). Iodide was injected as a conservative tracer with the CIC-CMC in both cases. The ratio between the CIC-CMC and iodide recovery was 76% and 45% in the high and low CMC loading experiments, respectively. During the low CMC loading experiment, the pumping rate was increased, leading to an additional CIC recovery of 2.5%. The results demonstrate the potentially high mobility of nZVI in fractured environments and the possibility for transport manipulation through the adjustment of stabilizer concentration and transport velocity.

Original languageEnglish
Pages (from-to)7849-7858
Number of pages10
JournalEnvironmental Science and Technology
Volume52
Issue number14
DOIs
StatePublished - 17 Jul 2018

ASJC Scopus subject areas

  • General Chemistry
  • Environmental Chemistry

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