First structural evidence of a Se-Br-Br halogen-bonded molecular complex

Yury V. Torubaev, Ivan V. Skabitskiy, Alina V. Pavlova, Alexander A. Pasynskii

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

The halogenation of 2,6-dibromo-9-selenabicyclo[3.3.1]-nonane 1 with 1 equivalent of molecular dihalogens (Br2 and I2) afforded a 1:1 molecular complex 1-X2 (X = Br (2); X = I (3)), while an excess of Br2 resulted in the ionic species [C8H12Br2SeBr]Br5- (4). X-ray crystallographic data and the nature of Se⋯Br non-covalent bonding in the solid state and solution is discussed.

Original languageEnglish
Pages (from-to)3606-3611
Number of pages6
JournalNew Journal of Chemistry
Volume41
Issue number9
DOIs
StatePublished - 1 Jan 2017
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • General Chemistry
  • Materials Chemistry

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