First structural evidence of a Se-Br-Br halogen-bonded molecular complex

Yury V. Torubaev; Ivan V. Skabitskiy; Alina V. Pavlova; Alexander A. Pasynskii

doi:10.1039/c6nj04096a

First structural evidence of a Se-Br-Br halogen-bonded molecular complex

Yury V. Torubaev, Ivan V. Skabitskiy, Alina V. Pavlova, Alexander A. Pasynskii

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

The halogenation of 2,6-dibromo-9-selenabicyclo[3.3.1]-nonane 1 with 1 equivalent of molecular dihalogens (Br₂ and I₂) afforded a 1:1 molecular complex 1-X₂ (X = Br (2); X = I (3)), while an excess of Br₂ resulted in the ionic species [C₈H₁₂Br₂SeBr]Br₅^- (4). X-ray crystallographic data and the nature of Se⋯Br non-covalent bonding in the solid state and solution is discussed.

Original language	English
Pages (from-to)	3606-3611
Number of pages	6
Journal	New Journal of Chemistry
Volume	41
Issue number	9
DOIs	https://doi.org/10.1039/c6nj04096a
State	Published - 1 Jan 2017
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Materials Chemistry

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title = "First structural evidence of a Se-Br-Br halogen-bonded molecular complex",

abstract = "The halogenation of 2,6-dibromo-9-selenabicyclo[3.3.1]-nonane 1 with 1 equivalent of molecular dihalogens (Br2 and I2) afforded a 1:1 molecular complex 1-X2 (X = Br (2); X = I (3)), while an excess of Br2 resulted in the ionic species [C8H12Br2SeBr]Br5- (4). X-ray crystallographic data and the nature of Se⋯Br non-covalent bonding in the solid state and solution is discussed.",

author = "Torubaev, {Yury V.} and Skabitskiy, {Ivan V.} and Pavlova, {Alina V.} and Pasynskii, {Alexander A.}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017.",

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doi = "10.1039/c6nj04096a",

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T1 - First structural evidence of a Se-Br-Br halogen-bonded molecular complex

AU - Torubaev, Yury V.

AU - Skabitskiy, Ivan V.

AU - Pavlova, Alina V.

AU - Pasynskii, Alexander A.

PY - 2017/1/1

Y1 - 2017/1/1

N2 - The halogenation of 2,6-dibromo-9-selenabicyclo[3.3.1]-nonane 1 with 1 equivalent of molecular dihalogens (Br2 and I2) afforded a 1:1 molecular complex 1-X2 (X = Br (2); X = I (3)), while an excess of Br2 resulted in the ionic species [C8H12Br2SeBr]Br5- (4). X-ray crystallographic data and the nature of Se⋯Br non-covalent bonding in the solid state and solution is discussed.

AB - The halogenation of 2,6-dibromo-9-selenabicyclo[3.3.1]-nonane 1 with 1 equivalent of molecular dihalogens (Br2 and I2) afforded a 1:1 molecular complex 1-X2 (X = Br (2); X = I (3)), while an excess of Br2 resulted in the ionic species [C8H12Br2SeBr]Br5- (4). X-ray crystallographic data and the nature of Se⋯Br non-covalent bonding in the solid state and solution is discussed.

UR - http://www.scopus.com/inward/record.url?scp=85021970043&partnerID=8YFLogxK

U2 - 10.1039/c6nj04096a

DO - 10.1039/c6nj04096a

M3 - Article

AN - SCOPUS:85021970043

SN - 1144-0546

VL - 41

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EP - 3611

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 9

ER -

First structural evidence of a Se-Br-Br halogen-bonded molecular complex

Abstract

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