Following in Operando the Structure Evolution-Induced Degradation in Printed Organic Solar Cells with Nonfullerene Small Molecule Acceptor

Understanding the degradation mechanisms of printed bulk-heterojunction (BHJ) organic solar cells during operation is essential to achieve long-term stability and realize real-world applications of organic photovoltaics. Herein, the degradation of printed organic solar cells based on the conjugated benzodithiophene polymer PBDB-T-SF and the nonfullerene small molecule acceptor IT-4F with 0.25 vol% 1,8-diiodooctane (DIO) solvent additive is studied in operando for two different donor:acceptor ratios. The inner nano-morphology is analyzed with grazing incidence small angle X-ray scattering (GISAXS), and current–voltage (I–V) characteristics are probed simultaneously. Irrespective of the mixing ratio, degradation occurs by the same degradation mechanism. A decrease in the short-circuit current density (J_SC) is identified to be the determining factor for the decline of the power conversion efficiency. The decrease in J_SC is induced by a reduction of the relative interface area between the conjugated polymer and the small molecule acceptor in the BHJ structure, resembling the morphological degradation of the active layer.