Formation of monomeric α-butylthioacrolein and its unusual reaction with 2,4-dinitrophenylhydrazine

N. A. Keiko; L. G. Stepanova; I. D. Kalikhman; M. G. Voronkov

doi:10.1007/BF01179474

Formation of monomeric α-butylthioacrolein and its unusual reaction with 2,4-dinitrophenylhydrazine

N. A. Keiko, L. G. Stepanova, I. D. Kalikhman, M. G. Voronkov

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of butylthioacetaldehyde with formaldehyde and diethylamine hydrochloride in neutral medium at 6-10° leads to the formation of the unstable α-butylacrolein. Treatment of the latter with 2,4-dinitrophenylhydrazine gives the 2,4-dinitrophenylhydrazone of acetone.

Original language	English
Pages (from-to)	595-596
Number of pages	2
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	26
Issue number	3
DOIs	https://doi.org/10.1007/BF01179474
State	Published - 1 Jan 1977
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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title = "Formation of monomeric α-butylthioacrolein and its unusual reaction with 2,4-dinitrophenylhydrazine",

abstract = "The reaction of butylthioacetaldehyde with formaldehyde and diethylamine hydrochloride in neutral medium at 6-10° leads to the formation of the unstable α-butylacrolein. Treatment of the latter with 2,4-dinitrophenylhydrazine gives the 2,4-dinitrophenylhydrazone of acetone.",

author = "Keiko, {N. A.} and Stepanova, {L. G.} and Kalikhman, {I. D.} and Voronkov, {M. G.}",

year = "1977",

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doi = "10.1007/BF01179474",

language = "English",

volume = "26",

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T1 - Formation of monomeric α-butylthioacrolein and its unusual reaction with 2,4-dinitrophenylhydrazine

AU - Keiko, N. A.

AU - Stepanova, L. G.

AU - Kalikhman, I. D.

AU - Voronkov, M. G.

PY - 1977/1/1

Y1 - 1977/1/1

N2 - The reaction of butylthioacetaldehyde with formaldehyde and diethylamine hydrochloride in neutral medium at 6-10° leads to the formation of the unstable α-butylacrolein. Treatment of the latter with 2,4-dinitrophenylhydrazine gives the 2,4-dinitrophenylhydrazone of acetone.

AB - The reaction of butylthioacetaldehyde with formaldehyde and diethylamine hydrochloride in neutral medium at 6-10° leads to the formation of the unstable α-butylacrolein. Treatment of the latter with 2,4-dinitrophenylhydrazine gives the 2,4-dinitrophenylhydrazone of acetone.

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U2 - 10.1007/BF01179474

DO - 10.1007/BF01179474

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AN - SCOPUS:34250302306

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VL - 26

SP - 595

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JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 3

ER -

Formation of monomeric α-butylthioacrolein and its unusual reaction with 2,4-dinitrophenylhydrazine

Abstract

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