Formation of Novel Phospha(PV)azenes via a Redox Condensation Process between Phosphorus(III) Compounds and Azodicarbonamide

Shmuel Bittner, Yonit Assaf, Martin Pomerantz

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12 Scopus citations

Abstract

A new class of N-acylphospha(PV)azenes (3, R3P=NCONHNHCONH2) was prepared by a rather novel redox condensation process using azodicarbonamide (1) and a variety of phosphines (2). The synthesis is simple and appears to be quite general. Structure proof rests on microanalysis as well as on IR, mass, and 1H NMR spectroscopy. A possible mechanism is proposed.

Original languageEnglish
Pages (from-to)99-101
Number of pages3
JournalJournal of Organic Chemistry
Volume47
Issue number1
DOIs
StatePublished - 1 Jan 1982

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