Formation of Pt-S-Mn groups in platinum triphenylphosphine complexes with cymanthrenylthiolate ligands

A. A. Pasynskii; I. V. Skabitsky; Yu V. Torubaev

doi:10.1007/s11172-006-0002-z

Formation of Pt-S-Mn groups in platinum triphenylphosphine complexes with cymanthrenylthiolate ligands

A. A. Pasynskii, I. V. Skabitsky, Yu V. Torubaev

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Stepwise decarbonylation of the platinum complex with cymanthrenylthiolate ligands cis-(Ph₃P)₂Pt[(SC₅H₄)Mn(CO) ₃]₂ (1) affords the cis-(Ph₃P) ₂Pt[SC₅H₄)Mn(CO)₃]-[(SC ₅H₄)Mn(CO)₂] (2) and cis-(Ph₃P) ₂Pt[(SC₅H₄)Mn(CO)₂]₂ (3) complexes. The replacement of one carbonyl group at the manganese atom with the lone electron pair of sulfur is accompanied by the formation of a new Mn-S bond giving rise to an unusual norbornane-type core. Complexes 1-3 were characterized by elemental analysis and IR spectroscopy. The structures of complexes 1-3 were established by single-crystal X-ray diffraction.

Original language	English
Pages (from-to)	1552-1556
Number of pages	5
Journal	Russian Chemical Bulletin
Volume	54
Issue number	7
DOIs	https://doi.org/10.1007/s11172-006-0002-z
State	Published - 1 Jul 2005
Externally published	Yes

Keywords

Cyclopentadienyl complexes
Cymanthrene
Heterometallic complexes
Manganese
Metal carbonyls
Metal chalcogenides
Platinum
X-ray diffraction analysis

ASJC Scopus subject areas

Chemistry (all)

Access to Document

10.1007/s11172-006-0002-z

Cite this

@article{15740c46c0cc4ef68d17d645b83b3831,

title = "Formation of Pt-S-Mn groups in platinum triphenylphosphine complexes with cymanthrenylthiolate ligands",

abstract = "Stepwise decarbonylation of the platinum complex with cymanthrenylthiolate ligands cis-(Ph3P)2Pt[(SC5H4)Mn(CO) 3]2 (1) affords the cis-(Ph3P) 2Pt[SC5H4)Mn(CO)3]-[(SC 5H4)Mn(CO)2] (2) and cis-(Ph3P) 2Pt[(SC5H4)Mn(CO)2]2 (3) complexes. The replacement of one carbonyl group at the manganese atom with the lone electron pair of sulfur is accompanied by the formation of a new Mn-S bond giving rise to an unusual norbornane-type core. Complexes 1-3 were characterized by elemental analysis and IR spectroscopy. The structures of complexes 1-3 were established by single-crystal X-ray diffraction.",

keywords = "Cyclopentadienyl complexes, Cymanthrene, Heterometallic complexes, Manganese, Metal carbonyls, Metal chalcogenides, Platinum, X-ray diffraction analysis",

author = "Pasynskii, {A. A.} and Skabitsky, {I. V.} and Torubaev, {Yu V.}",

note = "Funding Information: This study was financially supported by the Russian Foundation for Basic Research (Project No. 03 03 32730) and the Council on Grants of the President of the Russian Federation (State Program for Support of Young Scien tists, Grant NSh 2243.2003.03).",

year = "2005",

month = jul,

day = "1",

doi = "10.1007/s11172-006-0002-z",

language = "English",

volume = "54",

pages = "1552--1556",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer New York",

number = "7",

}

TY - JOUR

T1 - Formation of Pt-S-Mn groups in platinum triphenylphosphine complexes with cymanthrenylthiolate ligands

AU - Pasynskii, A. A.

AU - Skabitsky, I. V.

AU - Torubaev, Yu V.

N1 - Funding Information: This study was financially supported by the Russian Foundation for Basic Research (Project No. 03 03 32730) and the Council on Grants of the President of the Russian Federation (State Program for Support of Young Scien tists, Grant NSh 2243.2003.03).

PY - 2005/7/1

Y1 - 2005/7/1

N2 - Stepwise decarbonylation of the platinum complex with cymanthrenylthiolate ligands cis-(Ph3P)2Pt[(SC5H4)Mn(CO) 3]2 (1) affords the cis-(Ph3P) 2Pt[SC5H4)Mn(CO)3]-[(SC 5H4)Mn(CO)2] (2) and cis-(Ph3P) 2Pt[(SC5H4)Mn(CO)2]2 (3) complexes. The replacement of one carbonyl group at the manganese atom with the lone electron pair of sulfur is accompanied by the formation of a new Mn-S bond giving rise to an unusual norbornane-type core. Complexes 1-3 were characterized by elemental analysis and IR spectroscopy. The structures of complexes 1-3 were established by single-crystal X-ray diffraction.

AB - Stepwise decarbonylation of the platinum complex with cymanthrenylthiolate ligands cis-(Ph3P)2Pt[(SC5H4)Mn(CO) 3]2 (1) affords the cis-(Ph3P) 2Pt[SC5H4)Mn(CO)3]-[(SC 5H4)Mn(CO)2] (2) and cis-(Ph3P) 2Pt[(SC5H4)Mn(CO)2]2 (3) complexes. The replacement of one carbonyl group at the manganese atom with the lone electron pair of sulfur is accompanied by the formation of a new Mn-S bond giving rise to an unusual norbornane-type core. Complexes 1-3 were characterized by elemental analysis and IR spectroscopy. The structures of complexes 1-3 were established by single-crystal X-ray diffraction.

KW - Cyclopentadienyl complexes

KW - Cymanthrene

KW - Heterometallic complexes

KW - Manganese

KW - Metal carbonyls

KW - Metal chalcogenides

KW - Platinum

KW - X-ray diffraction analysis

UR - http://www.scopus.com/inward/record.url?scp=31344474934&partnerID=8YFLogxK

U2 - 10.1007/s11172-006-0002-z

DO - 10.1007/s11172-006-0002-z

M3 - Article

AN - SCOPUS:31344474934

SN - 1066-5285

VL - 54

SP - 1552

EP - 1556

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 7

ER -

Formation of Pt-S-Mn groups in platinum triphenylphosphine complexes with cymanthrenylthiolate ligands

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this