Functional monolayers with coordinatively embedded metalloporphyrins

Gonen Ashkenasy; Gregory Kalyuzhny; Jacqueline Libman; Israel Rubinstein; Abraham Shanzer

doi:10.1002/(SICI)1521-3773(19990503)38:9<1257::AID-ANIE1257>3.0.CO;2-H

Functional monolayers with coordinatively embedded metalloporphyrins

Gonen Ashkenasy
, Gregory Kalyuzhny
, Jacqueline Libman
, Israel Rubinstein
, Abraham Shanzer

Research output: Contribution to journal › Article › peer-review

49 Scopus citations

Abstract

Perpendicularly oriented iron porphyrins are absorbed onto a gold surface when interconnected long-chain diimidazolyl groups coordinate axially to the metal center from either side of the ring plane (see schematic representation). The stacking of the rings is simultaneously prevented. The monolayers have been characterized structurally and electrochemically.

Original language	English
Pages (from-to)	1257-1261
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	38
Issue number	9
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19990503)38:9<1257::AID-ANIE1257>3.0.CO;2-H
State	Published - 3 May 1999
Externally published	Yes

Keywords

Monolayers
N ligands
Porphyrinoids
Self-assembly

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/(SICI)1521-3773(19990503)38:9<1257::AID-ANIE1257>3.0.CO;2-H

Cite this

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abstract = "Perpendicularly oriented iron porphyrins are absorbed onto a gold surface when interconnected long-chain diimidazolyl groups coordinate axially to the metal center from either side of the ring plane (see schematic representation). The stacking of the rings is simultaneously prevented. The monolayers have been characterized structurally and electrochemically.",

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T1 - Functional monolayers with coordinatively embedded metalloporphyrins

AU - Ashkenasy, Gonen

AU - Kalyuzhny, Gregory

AU - Libman, Jacqueline

AU - Rubinstein, Israel

AU - Shanzer, Abraham

PY - 1999/5/3

Y1 - 1999/5/3

N2 - Perpendicularly oriented iron porphyrins are absorbed onto a gold surface when interconnected long-chain diimidazolyl groups coordinate axially to the metal center from either side of the ring plane (see schematic representation). The stacking of the rings is simultaneously prevented. The monolayers have been characterized structurally and electrochemically.

AB - Perpendicularly oriented iron porphyrins are absorbed onto a gold surface when interconnected long-chain diimidazolyl groups coordinate axially to the metal center from either side of the ring plane (see schematic representation). The stacking of the rings is simultaneously prevented. The monolayers have been characterized structurally and electrochemically.

KW - Monolayers

KW - N ligands

KW - Porphyrinoids

KW - Self-assembly

UR - https://www.scopus.com/pages/publications/0033519270

U2 - 10.1002/(SICI)1521-3773(19990503)38:9<1257::AID-ANIE1257>3.0.CO;2-H

DO - 10.1002/(SICI)1521-3773(19990503)38:9<1257::AID-ANIE1257>3.0.CO;2-H

M3 - Article

AN - SCOPUS:0033519270

SN - 1433-7851

VL - 38

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 9

ER -

Functional monolayers with coordinatively embedded metalloporphyrins

Abstract

Keywords

ASJC Scopus subject areas

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