Abstract
Activity coefficients and excess thermodynamic functions at infinite dilution were determined in the binary systems: diluent+solvate of uranyl nitrate, diluent+TBP, diluent+dodecane, and in the ternary system diluent+dodecane+TBP. Gas chromatography was used. The results agree well with vapour pressure measurements and solubility data. Particular attention was directed to the behaviour of water in these systems. The diluents used were benzene derivatives, paraffins, halogen-substituted hydrocarbons, cyclohexane, acetone, dioxane and carbon disulphide. The connection between the non-ideality of the organic phase and extraction equilibria is discussed.
Original language | English |
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Pages (from-to) | 185-194 |
Number of pages | 10 |
Journal | Transactions of the Faraday Society |
Volume | 63 |
DOIs | |
State | Published - 1 Jan 1967 |
Externally published | Yes |
ASJC Scopus subject areas
- General Engineering
- General Physics and Astronomy
- Physical and Theoretical Chemistry