TY - JOUR
T1 - Geminal interproton coupling constants in some methyl derivatives
AU - Lacey, M. J.
AU - Macdonald, C. G.
AU - Pross, A.
AU - Shannon, J. S.
AU - Sternhell, S.
N1 - Funding Information:
This work was supported by the Australian Research Grants Committee.
PY - 1970/1/1
Y1 - 1970/1/1
N2 - The geminal interproton coupling constants J(H-C-H) were obtained from the N.M.R. spectra of suitably deuterated compounds MenX where X = C, Ge, Sn, Pb, 0, S, I, N, and Li. The relation between the magnitudes of J(H-C-H), J(13C-H), and electronegativity of X in this series is explored and some correlations are proposed. The data for methyllithium do not fit with the remainder of the results. It is tentatively concluded that in this series of compounds J(H-C-H) is a periodic property.
AB - The geminal interproton coupling constants J(H-C-H) were obtained from the N.M.R. spectra of suitably deuterated compounds MenX where X = C, Ge, Sn, Pb, 0, S, I, N, and Li. The relation between the magnitudes of J(H-C-H), J(13C-H), and electronegativity of X in this series is explored and some correlations are proposed. The data for methyllithium do not fit with the remainder of the results. It is tentatively concluded that in this series of compounds J(H-C-H) is a periodic property.
UR - http://www.scopus.com/inward/record.url?scp=30244535359&partnerID=8YFLogxK
U2 - 10.1071/CH9701421
DO - 10.1071/CH9701421
M3 - Article
AN - SCOPUS:30244535359
SN - 0004-9425
VL - 23
SP - 1421
EP - 1429
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
IS - 7
ER -