Geminal interproton coupling constants in some methyl derivatives

M. J. Lacey; C. G. Macdonald; A. Pross; J. S. Shannon; S. Sternhell

doi:10.1071/CH9701421

Geminal interproton coupling constants in some methyl derivatives

M. J. Lacey
, C. G. Macdonald
, A. Pross
, J. S. Shannon
, S. Sternhell

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

The geminal interproton coupling constants J(H-C-H) were obtained from the N.M.R. spectra of suitably deuterated compounds Me_nX where X = C, Ge, Sn, Pb, 0, S, I, N, and Li. The relation between the magnitudes of J(H-C-H), J(¹³C-H), and electronegativity of X in this series is explored and some correlations are proposed. The data for methyllithium do not fit with the remainder of the results. It is tentatively concluded that in this series of compounds J(H-C-H) is a periodic property.

Original language	English
Pages (from-to)	1421-1429
Number of pages	9
Journal	Australian Journal of Chemistry
Volume	23
Issue number	7
DOIs	https://doi.org/10.1071/CH9701421
State	Published - 1 Jan 1970
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1071/CH9701421

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title = "Geminal interproton coupling constants in some methyl derivatives",

abstract = "The geminal interproton coupling constants J(H-C-H) were obtained from the N.M.R. spectra of suitably deuterated compounds MenX where X = C, Ge, Sn, Pb, 0, S, I, N, and Li. The relation between the magnitudes of J(H-C-H), J(13C-H), and electronegativity of X in this series is explored and some correlations are proposed. The data for methyllithium do not fit with the remainder of the results. It is tentatively concluded that in this series of compounds J(H-C-H) is a periodic property.",

author = "Lacey, \{M. J.\} and Macdonald, \{C. G.\} and A. Pross and Shannon, \{J. S.\} and S. Sternhell",

year = "1970",

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doi = "10.1071/CH9701421",

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T1 - Geminal interproton coupling constants in some methyl derivatives

AU - Lacey, M. J.

AU - Macdonald, C. G.

AU - Pross, A.

AU - Shannon, J. S.

AU - Sternhell, S.

PY - 1970/1/1

Y1 - 1970/1/1

N2 - The geminal interproton coupling constants J(H-C-H) were obtained from the N.M.R. spectra of suitably deuterated compounds MenX where X = C, Ge, Sn, Pb, 0, S, I, N, and Li. The relation between the magnitudes of J(H-C-H), J(13C-H), and electronegativity of X in this series is explored and some correlations are proposed. The data for methyllithium do not fit with the remainder of the results. It is tentatively concluded that in this series of compounds J(H-C-H) is a periodic property.

AB - The geminal interproton coupling constants J(H-C-H) were obtained from the N.M.R. spectra of suitably deuterated compounds MenX where X = C, Ge, Sn, Pb, 0, S, I, N, and Li. The relation between the magnitudes of J(H-C-H), J(13C-H), and electronegativity of X in this series is explored and some correlations are proposed. The data for methyllithium do not fit with the remainder of the results. It is tentatively concluded that in this series of compounds J(H-C-H) is a periodic property.

UR - https://www.scopus.com/pages/publications/30244535359

U2 - 10.1071/CH9701421

DO - 10.1071/CH9701421

M3 - Article

AN - SCOPUS:30244535359

SN - 0004-9425

VL - 23

SP - 1421

EP - 1429

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 7

ER -

Geminal interproton coupling constants in some methyl derivatives

Abstract

ASJC Scopus subject areas

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