Germylation reaction of phenoxyacetylene

O. A. Kruglaya; G. S. Lyashenko; A. Kh Filippova; V. V. Keiko; I. D. Kalikhman; N. S. Vyazankin

doi:10.1007/BF01106681

Germylation reaction of phenoxyacetylene

O. A. Kruglaya
, G. S. Lyashenko
, A. Kh Filippova
, V. V. Keiko
, I. D. Kalikhman
, N. S. Vyazankin

Research output: Contribution to journal › Article › peer-review

Abstract

1. The metallation process dominates in reaction of (C₂H₅)₃GeLi with phenoxyacetylene, leading to C₆H₅OC=CLi. Addition at the acetylene bond proceeds nonregiospecifically with formation of α- and cisβ-adducts. 2. Addition of (C₂H₅)₃GeH to phenoxyacetylene under the effect of Spaier catalyst leads to a mixture of α-, cis-β-, and trans-β-adducts.

Original language	English
Pages (from-to)	669-671
Number of pages	3
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	25
Issue number	3
DOIs	https://doi.org/10.1007/BF01106681
State	Published - 1 Jan 1976
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1007/BF01106681

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title = "Germylation reaction of phenoxyacetylene",

abstract = "1. The metallation process dominates in reaction of (C2H5)3GeLi with phenoxyacetylene, leading to C6H5OC=CLi. Addition at the acetylene bond proceeds nonregiospecifically with formation of α- and cisβ-adducts. 2. Addition of (C2H5)3GeH to phenoxyacetylene under the effect of Spaier catalyst leads to a mixture of α-, cis-β-, and trans-β-adducts.",

author = "Kruglaya, \{O. A.\} and Lyashenko, \{G. S.\} and Filippova, \{A. Kh\} and Keiko, \{V. V.\} and Kalikhman, \{I. D.\} and Vyazankin, \{N. S.\}",

year = "1976",

month = jan,

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doi = "10.1007/BF01106681",

language = "English",

volume = "25",

pages = "669--671",

journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

issn = "0568-5230",

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number = "3",

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TY - JOUR

T1 - Germylation reaction of phenoxyacetylene

AU - Kruglaya, O. A.

AU - Lyashenko, G. S.

AU - Filippova, A. Kh

AU - Keiko, V. V.

AU - Kalikhman, I. D.

AU - Vyazankin, N. S.

PY - 1976/1/1

Y1 - 1976/1/1

N2 - 1. The metallation process dominates in reaction of (C2H5)3GeLi with phenoxyacetylene, leading to C6H5OC=CLi. Addition at the acetylene bond proceeds nonregiospecifically with formation of α- and cisβ-adducts. 2. Addition of (C2H5)3GeH to phenoxyacetylene under the effect of Spaier catalyst leads to a mixture of α-, cis-β-, and trans-β-adducts.

AB - 1. The metallation process dominates in reaction of (C2H5)3GeLi with phenoxyacetylene, leading to C6H5OC=CLi. Addition at the acetylene bond proceeds nonregiospecifically with formation of α- and cisβ-adducts. 2. Addition of (C2H5)3GeH to phenoxyacetylene under the effect of Spaier catalyst leads to a mixture of α-, cis-β-, and trans-β-adducts.

UR - https://www.scopus.com/pages/publications/34250292021

U2 - 10.1007/BF01106681

DO - 10.1007/BF01106681

M3 - Article

AN - SCOPUS:34250292021

SN - 0568-5230

VL - 25

SP - 669

EP - 671

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 3

ER -

Germylation reaction of phenoxyacetylene

Abstract

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