Abstract
Perovskite Solar Cells (PSCs) have attracted attention due to their low cost, easy solution processability, high efficiency, and scalability. However, the benchmark expensive hole transport material (HTM) 2,2′,7,7′-tetrakis[N, N-di(4-methoxyphenyl)amino]-9,9′-spirobifluorene (Spiro-MeOTAD), which is traditionally solution-processed with toxic solvents such as chlorobenzene (CB), dichlorobenzene (DCB), or toluene, is a bottleneck. To address this issue, this work investigates the implementation of Zn(II), Cu(II), or Co(II) tetra-tert-butylphthalocyanines (TBU4-Cu, TBU4-Zn, TBU4-Co), established macrocyclic derivatives whose synthesis and processing inside the devices have been redesigned to be more environmentally sustainable and cost-effective by substituting conventional solvents with greener alternatives such as anisole, propane-1,2-diol, and their mixture, as dopant-free HTMs in planar n-i-p PSCs. The anisole-processed HTMs provided power conversion efficiencies (PCE) up to 12.27% for TBU4-Cu and 11.73% for TBU4-Zn, with better photovoltaic parameters than the corresponding cells made with chlorobenzene for which the best results obtained were, respectively, 12.22% and 10.81%.
Original language | English |
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Article number | 3643 |
Journal | Energies |
Volume | 16 |
Issue number | 9 |
DOIs | |
State | Published - 1 May 2023 |
Externally published | Yes |
Keywords
- anisole
- green synthesis
- hybrid perovskites
- porphyrinoids
- propylene glycol
ASJC Scopus subject areas
- Renewable Energy, Sustainability and the Environment
- Fuel Technology
- Engineering (miscellaneous)
- Energy Engineering and Power Technology
- Energy (miscellaneous)
- Control and Optimization
- Electrical and Electronic Engineering