Guests on different internal capsule sites exchange with each other and with the outside

Olga Petina, Dieter Rehder, Erhard T.K. Haupt, Alina Grego, Ira A. Weinstock, Alice Merca, Hartmut Bögge, Julia Szakács, Achim Müller

Research output: Contribution to journalArticlepeer-review

43 Scopus citations

Abstract

In and out: Compartmentalization in a porous polyoxometalate capsule (see structure, red and blue polyhedra) allows acetate ions (green/red or orange/red), coordinated to different internal sites, to exchange not only with each other (yellow double arrow) but also with those outside in bulk aqueous solution.

Original languageEnglish
Pages (from-to)410-414
Number of pages5
JournalAngewandte Chemie - International Edition
Volume50
Issue number2
DOIs
StatePublished - 10 Jan 2011

Keywords

  • NMR spectroscopy
  • capsules
  • equilibria
  • guest exchange
  • polyoxometalates

ASJC Scopus subject areas

  • Catalysis
  • Chemistry (all)

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