Halogen and Hydrogen Bonds in Co-crystalline Ferrocenium Organotellurium Halide Salts

Yu V. Torubaev; K. A. Lyssenko; A. E. Popova

doi:10.1134/S1070328419110095

Halogen and Hydrogen Bonds in Co-crystalline Ferrocenium Organotellurium Halide Salts

Yu V. Torubaev, K. A. Lyssenko, A. E. Popova

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Abstract: The reactions of ferrocene and decamethylferrocene with vinyltellurium trichloride Ph(Cl)C= C(Ph)TeCl₃ afford unusual co-crystalline salts [Cp₂Fe]⁺Cl^–Ph(Cl)C=C(Ph)TeCl₂OH (I) and [(C₅Me₅)₂Fe]⁺Cl^–(Ph(Cl)C=C(Ph)TeCl₂OH) (II). The Ph(Cl)C=C(Ph)TeCl₂OH molecule in these salts is neutral and forms only non-covalent (hydrogen and chalcogen) bonds with the chloride ion. The hydrolytic replacement of a chlorine atom not involved in the three-center four-electron Cl–Te–Cl bond in Ph(Cl)C=C(Ph)TeCl₃ is due to the general moisture sensitivity of organic telluriium halides, and the accompanying oxidation of ferrocene is not a necessary condition for the formation of Ph(Cl)C=C(Ph)TeCl₂OH (III). (CCDC nos. 1908530 (I), 1908531 (II), 1908532 (III).).

Original language	English
Pages (from-to)	788-794
Number of pages	7
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	45
Issue number	11
DOIs	https://doi.org/10.1134/S1070328419110095
State	Published - 1 Nov 2019
Externally published	Yes

Keywords

X-ray diffraction
chalcogen bonds
co-crystalline salts
ferrocene
halogen bonds
hydrogen bonds
tellurium halides

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

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title = "Halogen and Hydrogen Bonds in Co-crystalline Ferrocenium Organotellurium Halide Salts",

abstract = "Abstract: The reactions of ferrocene and decamethylferrocene with vinyltellurium trichloride Ph(Cl)C= C(Ph)TeCl3 afford unusual co-crystalline salts [Cp2Fe]+Cl–Ph(Cl)C=C(Ph)TeCl2OH (I) and [(C5Me5)2Fe]+Cl–(Ph(Cl)C=C(Ph)TeCl2OH) (II). The Ph(Cl)C=C(Ph)TeCl2OH molecule in these salts is neutral and forms only non-covalent (hydrogen and chalcogen) bonds with the chloride ion. The hydrolytic replacement of a chlorine atom not involved in the three-center four-electron Cl–Te–Cl bond in Ph(Cl)C=C(Ph)TeCl3 is due to the general moisture sensitivity of organic telluriium halides, and the accompanying oxidation of ferrocene is not a necessary condition for the formation of Ph(Cl)C=C(Ph)TeCl2OH (III). (CCDC nos. 1908530 (I), 1908531 (II), 1908532 (III).).",

keywords = "X-ray diffraction, chalcogen bonds, co-crystalline salts, ferrocene, halogen bonds, hydrogen bonds, tellurium halides",

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T1 - Halogen and Hydrogen Bonds in Co-crystalline Ferrocenium Organotellurium Halide Salts

AU - Torubaev, Yu V.

AU - Lyssenko, K. A.

AU - Popova, A. E.

PY - 2019/11/1

Y1 - 2019/11/1

N2 - Abstract: The reactions of ferrocene and decamethylferrocene with vinyltellurium trichloride Ph(Cl)C= C(Ph)TeCl3 afford unusual co-crystalline salts [Cp2Fe]+Cl–Ph(Cl)C=C(Ph)TeCl2OH (I) and [(C5Me5)2Fe]+Cl–(Ph(Cl)C=C(Ph)TeCl2OH) (II). The Ph(Cl)C=C(Ph)TeCl2OH molecule in these salts is neutral and forms only non-covalent (hydrogen and chalcogen) bonds with the chloride ion. The hydrolytic replacement of a chlorine atom not involved in the three-center four-electron Cl–Te–Cl bond in Ph(Cl)C=C(Ph)TeCl3 is due to the general moisture sensitivity of organic telluriium halides, and the accompanying oxidation of ferrocene is not a necessary condition for the formation of Ph(Cl)C=C(Ph)TeCl2OH (III). (CCDC nos. 1908530 (I), 1908531 (II), 1908532 (III).).

AB - Abstract: The reactions of ferrocene and decamethylferrocene with vinyltellurium trichloride Ph(Cl)C= C(Ph)TeCl3 afford unusual co-crystalline salts [Cp2Fe]+Cl–Ph(Cl)C=C(Ph)TeCl2OH (I) and [(C5Me5)2Fe]+Cl–(Ph(Cl)C=C(Ph)TeCl2OH) (II). The Ph(Cl)C=C(Ph)TeCl2OH molecule in these salts is neutral and forms only non-covalent (hydrogen and chalcogen) bonds with the chloride ion. The hydrolytic replacement of a chlorine atom not involved in the three-center four-electron Cl–Te–Cl bond in Ph(Cl)C=C(Ph)TeCl3 is due to the general moisture sensitivity of organic telluriium halides, and the accompanying oxidation of ferrocene is not a necessary condition for the formation of Ph(Cl)C=C(Ph)TeCl2OH (III). (CCDC nos. 1908530 (I), 1908531 (II), 1908532 (III).).

KW - X-ray diffraction

KW - chalcogen bonds

KW - co-crystalline salts

KW - ferrocene

KW - halogen bonds

KW - hydrogen bonds

KW - tellurium halides

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Halogen and Hydrogen Bonds in Co-crystalline Ferrocenium Organotellurium Halide Salts

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