Heterogenization of Rh-MeDuPHOS by occlusion in polyvinyl alcohol films

Adi Wolfson; Shimona Geresh; Moshe Gottlieb; Moti Herskowitz

doi:10.1016/S0957-4166(02)00083-6

Heterogenization of Rh-MeDuPHOS by occlusion in polyvinyl alcohol films

Adi Wolfson, Shimona Geresh, Moshe Gottlieb, Moti Herskowitz

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

A new recyclable chiral heterogeneous catalytic system was obtained by the occlusion of Rh-MeDuPHOS in polyvinyl alcohol film. Enantiomeric excess of up to 96% was achieved in the asymmetric hydrogenation of methyl 2-acetamidoacrylate in aqueous medium.

Original language	English
Pages (from-to)	465-468
Number of pages	4
Journal	Tetrahedron Asymmetry
Volume	13
Issue number	5
DOIs	https://doi.org/10.1016/S0957-4166(02)00083-6
State	Published - 5 Apr 2002

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1016/S0957-4166(02)00083-6

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title = "Heterogenization of Rh-MeDuPHOS by occlusion in polyvinyl alcohol films",

abstract = "A new recyclable chiral heterogeneous catalytic system was obtained by the occlusion of Rh-MeDuPHOS in polyvinyl alcohol film. Enantiomeric excess of up to 96% was achieved in the asymmetric hydrogenation of methyl 2-acetamidoacrylate in aqueous medium.",

author = "Adi Wolfson and Shimona Geresh and Moshe Gottlieb and Moti Herskowitz",

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T1 - Heterogenization of Rh-MeDuPHOS by occlusion in polyvinyl alcohol films

AU - Wolfson, Adi

AU - Geresh, Shimona

AU - Gottlieb, Moshe

AU - Herskowitz, Moti

PY - 2002/4/5

Y1 - 2002/4/5

N2 - A new recyclable chiral heterogeneous catalytic system was obtained by the occlusion of Rh-MeDuPHOS in polyvinyl alcohol film. Enantiomeric excess of up to 96% was achieved in the asymmetric hydrogenation of methyl 2-acetamidoacrylate in aqueous medium.

AB - A new recyclable chiral heterogeneous catalytic system was obtained by the occlusion of Rh-MeDuPHOS in polyvinyl alcohol film. Enantiomeric excess of up to 96% was achieved in the asymmetric hydrogenation of methyl 2-acetamidoacrylate in aqueous medium.

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U2 - 10.1016/S0957-4166(02)00083-6

DO - 10.1016/S0957-4166(02)00083-6

M3 - Article

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SN - 0957-4166

VL - 13

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EP - 468

JO - Tetrahedron Asymmetry

JF - Tetrahedron Asymmetry

IS - 5

ER -

Heterogenization of Rh-MeDuPHOS by occlusion in polyvinyl alcohol films

Abstract

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