Hexacoordinate complexes of silacyclobutane: Spontaneous ring opening and rearrangement

Boris Gostevskii; Inna Kalikhman; Claire A. Tessier; Matthew J. Panzner; Wiley J. Youngs; Daniel Kost

doi:10.1021/om0505559

Hexacoordinate complexes of silacyclobutane: Spontaneous ring opening and rearrangement

Boris Gostevskii, Inna Kalikhman, Claire A. Tessier, Matthew J. Panzner, Wiley J. Youngs, Daniel Kost

Department of Chemistry

Research output: Contribution to journal › Review article › peer-review

21 Scopus citations

Abstract

The title compounds were prepared and were found to undergo ring opening and molecular rearrangement under mild conditions and no catalysis, forming a carbon - carbon bond and closing a new chelate ring. The rearrangement product depends on whether a-protons are present. Reactants and products are characterized by crystal structures.

Original language	English
Pages (from-to)	5786-5788
Number of pages	3
Journal	Organometallics
Volume	24
Issue number	24
DOIs	https://doi.org/10.1021/om0505559
State	Published - 21 Nov 2005

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om0505559

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@article{a84816871967445f91feb4d54d25990f,

title = "Hexacoordinate complexes of silacyclobutane: Spontaneous ring opening and rearrangement",

abstract = "The title compounds were prepared and were found to undergo ring opening and molecular rearrangement under mild conditions and no catalysis, forming a carbon - carbon bond and closing a new chelate ring. The rearrangement product depends on whether a-protons are present. Reactants and products are characterized by crystal structures.",

author = "Boris Gostevskii and Inna Kalikhman and Tessier, {Claire A.} and Panzner, {Matthew J.} and Youngs, {Wiley J.} and Daniel Kost",

year = "2005",

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doi = "10.1021/om0505559",

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TY - JOUR

T1 - Hexacoordinate complexes of silacyclobutane

T2 - Spontaneous ring opening and rearrangement

AU - Gostevskii, Boris

AU - Kalikhman, Inna

AU - Tessier, Claire A.

AU - Panzner, Matthew J.

AU - Youngs, Wiley J.

AU - Kost, Daniel

PY - 2005/11/21

Y1 - 2005/11/21

N2 - The title compounds were prepared and were found to undergo ring opening and molecular rearrangement under mild conditions and no catalysis, forming a carbon - carbon bond and closing a new chelate ring. The rearrangement product depends on whether a-protons are present. Reactants and products are characterized by crystal structures.

AB - The title compounds were prepared and were found to undergo ring opening and molecular rearrangement under mild conditions and no catalysis, forming a carbon - carbon bond and closing a new chelate ring. The rearrangement product depends on whether a-protons are present. Reactants and products are characterized by crystal structures.

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U2 - 10.1021/om0505559

DO - 10.1021/om0505559

M3 - Review article

AN - SCOPUS:28944446991

SN - 0276-7333

VL - 24

SP - 5786

EP - 5788

JO - Organometallics

JF - Organometallics

IS - 24

ER -

Hexacoordinate complexes of silacyclobutane: Spontaneous ring opening and rearrangement

Abstract

ASJC Scopus subject areas

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