TY - JOUR
T1 - High-spin heteronuclear cyanometalates
T2 - Proceedings of the 1998 6th International Conference on Molecule Based Magnets (ICMM'98)
AU - Ostrovsky, Sergey M.
AU - Scuiller, Ariane
AU - Marvaud, Valerie
AU - Tsukerblat, Boris S.
AU - Verdaguer, Michel
N1 - Funding Information:
B.T. is indebted to the French ministry of education for a PAST grant; S.0 thanks ESF for research grant. We acknowledge T.Mallah for fruitfbl discussion at preliminary steps of the study.
PY - 1999/1/1
Y1 - 1999/1/1
N2 - Using the irreducible tensor operator technique we develop a computational approach to the problem of g-tensors for the heteronuclear polymetallic systems consisting of the arbitrary number of coupled paramagnetic ions. We deduce the effective g-values for the family of the heterometallic CrIIINiIIncyanometalates (n = 2,3,4,5,6) possessing different topologies. For CrIIINiII6 complexes a good fit to experimental μ(T) is achieved. For CrIIICuII6 the local anisotropy of g for CuII ions is taken into account.
AB - Using the irreducible tensor operator technique we develop a computational approach to the problem of g-tensors for the heteronuclear polymetallic systems consisting of the arbitrary number of coupled paramagnetic ions. We deduce the effective g-values for the family of the heterometallic CrIIINiIIncyanometalates (n = 2,3,4,5,6) possessing different topologies. For CrIIINiII6 complexes a good fit to experimental μ(T) is achieved. For CrIIICuII6 the local anisotropy of g for CuII ions is taken into account.
UR - http://www.scopus.com/inward/record.url?scp=0033318532&partnerID=8YFLogxK
U2 - 10.1080/10587259908028882
DO - 10.1080/10587259908028882
M3 - Conference article
AN - SCOPUS:0033318532
SN - 1058-725X
VL - 335
SP - 1103
EP - 1112
JO - Molecular Crystals and Liquid Crystals
JF - Molecular Crystals and Liquid Crystals
Y2 - 12 September 1998 through 17 September 1998
ER -