Highly efficient functional GexPb1-xTe based thermoelectric alloys

Yaniv Gelbstein, Joseph Davidow

Research output: Contribution to journalArticlepeer-review

114 Scopus citations


Methods for enhancement of the direct thermal to electrical energy conversion efficiency, upon development of advanced thermoelectric materials, are constantly investigated mainly for efficient implementation of thermoelectric devices in automotive vehicles, for converting the waste heat generated in such engines into useful electrical power and thereby reduction of the fuel consumption and CO2 emission levels. It was recently shown that GeTe based compounds and specifically GeTe-PbTe rich alloys are efficient p-type thermoelectric compositions. In the current research, Bi2Te3 doping and PbTe alloying effects in GexPb1-xTe alloys, subjected to phase separation reactions, were investigated for identifying the phase separation potential for enhancement of the thermoelectric properties beyond a pure alloying effect. All of the investigated compositions exhibit maximal dimensionless figure of merit, ZT, values beyond 1, with the extraordinary value of 2.1 found for the 5% Bi2Te3 doped-Ge0.87Pb0.13Te composition, considered as among the highest ever reported.

Original languageEnglish
Pages (from-to)20120-20126
Number of pages7
JournalPhysical Chemistry Chemical Physics
Issue number37
StatePublished - 27 Aug 2014

ASJC Scopus subject areas

  • General Physics and Astronomy
  • Physical and Theoretical Chemistry


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