Highly polar stacking interactions wrap inorganics in organics: Lone-pair-π-hole interactions between the PdO₄core and electron-deficient arenes

Keyphrases

• Acidic Surface 33%
• Arenes 100%
• Aromatic Ring 33%
• Biphenyl 33%
• Carboxylate 33%
• Co-crystallization 33%
• Cocrystal 33%
• Density Functional Theory 33%
• Electron-deficient 33%
• Electron-deficient Arenes 100%
• Electron-rich 33%
• Energy Frameworks 33%
• Halogen Bonding 33%
• Hirshfeld Surface Analysis 33%
• Hole Interaction 100%
• Inorganic-organic 33%
• Iodine 66%
• Iodine-free 33%
• Lone Pair 100%
• Molecular Electrostatic Potential Surface 33%
• Noncovalent Interactions 33%
• Nucleophile 33%
• Octafluoronaphthalene 33%
• Palladium Acetate 33%
• Perfluoroarenes 33%
• Potential Surface Analysis 33%
• Quantum Theory of Atoms in Molecules (QTAIM) 33%
• Single Crystal X-ray Diffraction (SCXRD) 33%
• Stacking Interactions 100%

Chemistry

• Aromatic Structure 100%
• Biphenyl 100%
• Co Crystallization 100%
• Density Functional Theory Study 100%
• Electrostatic Potential 100%
• Hirshfeld Surface 100%
• Nucleophile 100%
• Palladium 100%
• Single Crystalline Solid 100%
• Surface Analysis 100%
• X-Ray Diffractometry 100%