Abstract
We consider the hybridization of atomic and nearly free states in the mixed-valence systems within the procedure which allows to separate in special cases the Hubbard and Fermi branches of elementary excitations. We discuss the physical consequences of this separation and propose a mechanism of phase transition with the valence change where the localized moments of the f-states disappear in the low-temperature phase due to the Mott-Hubbard transition.
Original language | English |
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Pages (from-to) | 323-328 |
Number of pages | 6 |
Journal | Solid State Communications |
Volume | 33 |
Issue number | 3 |
DOIs | |
State | Published - 1 Jan 1980 |
Externally published | Yes |
ASJC Scopus subject areas
- Chemistry (all)
- Condensed Matter Physics
- Materials Chemistry