Abstract
We consider the hybridization of atomic and nearly free states in the mixed-valence systems within the procedure which allows to separate in special cases the Hubbard and Fermi branches of elementary excitations. We discuss the physical consequences of this separation and propose a mechanism of phase transition with the valence change where the localized moments of the f-states disappear in the low-temperature phase due to the Mott-Hubbard transition.
| Original language | English |
|---|---|
| Pages (from-to) | 323-328 |
| Number of pages | 6 |
| Journal | Solid State Communications |
| Volume | 33 |
| Issue number | 3 |
| DOIs | |
| State | Published - 1 Jan 1980 |
| Externally published | Yes |
ASJC Scopus subject areas
- General Chemistry
- Condensed Matter Physics
- Materials Chemistry