Hydrolytic cleavage of 2-(tetrahydro-α-furyl)-5,5-dimethyltetrahydrofuran-4-one

A. S. Medvedeva; M. M. Demina; I. D. Kalikhman; M. G. Voronkov

doi:10.1007/BF01152877

Hydrolytic cleavage of 2-(tetrahydro-α-furyl)-5,5-dimethyltetrahydrofuran-4-one

A. S. Medvedeva, M. M. Demina, I. D. Kalikhman, M. G. Voronkov

Research output: Contribution to journal › Article › peer-review

Abstract

2-(Tetrahydro-α-furyl)-5,5-dimethyltetrahydrofuran-4-one under the action of catalytic quantities of concentrated hydrochloric acid readily undergoes hydrolytic cleavage into 2-(3′-hydroxypropynyl)-5, 5-dimethyldihydrofuran-4-one. The isomeric ketone 2-(tetrahydro-α-furyl)-5, 5-dimethyltetrahydrofuran-3-one does not change under these conditions.

Original language	English
Pages (from-to)	2686-2688
Number of pages	3
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	24
Issue number	12
DOIs	https://doi.org/10.1007/BF01152877
State	Published - 1 Dec 1975
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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title = "Hydrolytic cleavage of 2-(tetrahydro-α-furyl)-5,5-dimethyltetrahydrofuran-4-one",

abstract = "2-(Tetrahydro-α-furyl)-5,5-dimethyltetrahydrofuran-4-one under the action of catalytic quantities of concentrated hydrochloric acid readily undergoes hydrolytic cleavage into 2-(3′-hydroxypropynyl)-5, 5-dimethyldihydrofuran-4-one. The isomeric ketone 2-(tetrahydro-α-furyl)-5, 5-dimethyltetrahydrofuran-3-one does not change under these conditions.",

author = "Medvedeva, {A. S.} and Demina, {M. M.} and Kalikhman, {I. D.} and Voronkov, {M. G.}",

year = "1975",

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doi = "10.1007/BF01152877",

language = "English",

volume = "24",

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journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

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T1 - Hydrolytic cleavage of 2-(tetrahydro-α-furyl)-5,5-dimethyltetrahydrofuran-4-one

AU - Medvedeva, A. S.

AU - Demina, M. M.

AU - Kalikhman, I. D.

AU - Voronkov, M. G.

PY - 1975/12/1

Y1 - 1975/12/1

N2 - 2-(Tetrahydro-α-furyl)-5,5-dimethyltetrahydrofuran-4-one under the action of catalytic quantities of concentrated hydrochloric acid readily undergoes hydrolytic cleavage into 2-(3′-hydroxypropynyl)-5, 5-dimethyldihydrofuran-4-one. The isomeric ketone 2-(tetrahydro-α-furyl)-5, 5-dimethyltetrahydrofuran-3-one does not change under these conditions.

AB - 2-(Tetrahydro-α-furyl)-5,5-dimethyltetrahydrofuran-4-one under the action of catalytic quantities of concentrated hydrochloric acid readily undergoes hydrolytic cleavage into 2-(3′-hydroxypropynyl)-5, 5-dimethyldihydrofuran-4-one. The isomeric ketone 2-(tetrahydro-α-furyl)-5, 5-dimethyltetrahydrofuran-3-one does not change under these conditions.

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U2 - 10.1007/BF01152877

DO - 10.1007/BF01152877

M3 - Article

AN - SCOPUS:34250399445

SN - 0568-5230

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JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 12

ER -

Hydrolytic cleavage of 2-(tetrahydro-α-furyl)-5,5-dimethyltetrahydrofuran-4-one

Abstract

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