Hydrosilylation reactions of hydrosilatrane and 2-methyl-6-ethyl-1,3-dioxa-6-aza-2-silacyclooctane

M. G. Voronkov; V. I. Rakhlin; S. N. Adamovich; L. P. Petukhov; R. G. Mirskov; N. K. Yarosh; A. L. Kuznetsov; M. V. Sigalov

doi:10.1007/BF00954236

Hydrosilylation reactions of hydrosilatrane and 2-methyl-6-ethyl-1,3-dioxa-6-aza-2-silacyclooctane

M. G. Voronkov, V. I. Rakhlin, S. N. Adamovich, L. P. Petukhov, R. G. Mirskov, N. K. Yarosh, A. L. Kuznetsov, M. V. Sigalov

Research output: Contribution to journal › Article › peer-review

Abstract

1-Hydrosilatrane does not react with monosubstituted ethylenes (or acetylenes) either in the presence of platinum or rhodium complexes or upon initiation of the reactions using organic peroxides, UV irradiation, or thermal methods. By contrast, 2-methyl-6-ethyl-1,3-dioxa-6-aza-2-silacyclooctane readily takes part in hydrosilylation of the indicated unsaturated compounds when Rhacac (CO)₂ is present.

Original language	English
Pages (from-to)	819-821
Number of pages	3
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	35
Issue number	4
DOIs	https://doi.org/10.1007/BF00954236
State	Published - 1 Apr 1986
Externally published	Yes

ASJC Scopus subject areas

Chemistry (all)

Access to Document

10.1007/BF00954236

Cite this

Voronkov, M. G., Rakhlin, V. I., Adamovich, S. N., Petukhov, L. P., Mirskov, R. G., Yarosh, N. K., Kuznetsov, A. L., & Sigalov, M. V. (1986). Hydrosilylation reactions of hydrosilatrane and 2-methyl-6-ethyl-1,3-dioxa-6-aza-2-silacyclooctane. Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 35(4), 819-821. https://doi.org/10.1007/BF00954236

@article{85bf4f5c308a4bc08c0b9f76ba3bd695,

title = "Hydrosilylation reactions of hydrosilatrane and 2-methyl-6-ethyl-1,3-dioxa-6-aza-2-silacyclooctane",

abstract = "1-Hydrosilatrane does not react with monosubstituted ethylenes (or acetylenes) either in the presence of platinum or rhodium complexes or upon initiation of the reactions using organic peroxides, UV irradiation, or thermal methods. By contrast, 2-methyl-6-ethyl-1,3-dioxa-6-aza-2-silacyclooctane readily takes part in hydrosilylation of the indicated unsaturated compounds when Rhacac (CO)2 is present.",

author = "Voronkov, {M. G.} and Rakhlin, {V. I.} and Adamovich, {S. N.} and Petukhov, {L. P.} and Mirskov, {R. G.} and Yarosh, {N. K.} and Kuznetsov, {A. L.} and Sigalov, {M. V.}",

year = "1986",

month = apr,

day = "1",

doi = "10.1007/BF00954236",

language = "English",

volume = "35",

pages = "819--821",

journal = "Bulletin of the Academy of Sciences of the USSR Division of Chemical Science",

issn = "0568-5230",

publisher = "Springer New York",

number = "4",

}

TY - JOUR

T1 - Hydrosilylation reactions of hydrosilatrane and 2-methyl-6-ethyl-1,3-dioxa-6-aza-2-silacyclooctane

AU - Voronkov, M. G.

AU - Rakhlin, V. I.

AU - Adamovich, S. N.

AU - Petukhov, L. P.

AU - Mirskov, R. G.

AU - Yarosh, N. K.

AU - Kuznetsov, A. L.

AU - Sigalov, M. V.

PY - 1986/4/1

Y1 - 1986/4/1

N2 - 1-Hydrosilatrane does not react with monosubstituted ethylenes (or acetylenes) either in the presence of platinum or rhodium complexes or upon initiation of the reactions using organic peroxides, UV irradiation, or thermal methods. By contrast, 2-methyl-6-ethyl-1,3-dioxa-6-aza-2-silacyclooctane readily takes part in hydrosilylation of the indicated unsaturated compounds when Rhacac (CO)2 is present.

AB - 1-Hydrosilatrane does not react with monosubstituted ethylenes (or acetylenes) either in the presence of platinum or rhodium complexes or upon initiation of the reactions using organic peroxides, UV irradiation, or thermal methods. By contrast, 2-methyl-6-ethyl-1,3-dioxa-6-aza-2-silacyclooctane readily takes part in hydrosilylation of the indicated unsaturated compounds when Rhacac (CO)2 is present.

UR - http://www.scopus.com/inward/record.url?scp=34250131322&partnerID=8YFLogxK

U2 - 10.1007/BF00954236

DO - 10.1007/BF00954236

M3 - Article

AN - SCOPUS:34250131322

SN - 0568-5230

VL - 35

SP - 819

EP - 821

JO - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

JF - Bulletin of the Academy of Sciences of the USSR Division of Chemical Science

IS - 4

ER -

Hydrosilylation reactions of hydrosilatrane and 2-methyl-6-ethyl-1,3-dioxa-6-aza-2-silacyclooctane

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this