@article{d33c6a9dd7c44fb4b7493fb8746a64f2,
title = "Hydroxylation and amidation of aromatic carbonyl compounds",
abstract = "Ortho-para-Hydroxylation and acetamidation of aromatic carbonyl compounds has been accomplished anodically.",
author = "So, {Ying Hung} and Becker, {James Y.} and Miller, {Larry L.}",
note = "Funding Information: Overall it is a two- electron mechanism. In the case of hydroxylation the trifluoroacetate product, ArO,CCF,, should be stable in the anolyte, but will be hydrolysed by work-up with aqueous NaHCO,. It is presumably important that the easily oxidized phenol is not present in the anolyte. Whether the oxidized intermediate can be classified as having a n-vacancy or a vacancy in a non-bonding oxygen orbital4 will be discussed elsewhere. It is, however, clear that a 7-cation radical intermediate could account for the above observations. This work was supported by the donors of the Petroleum Research Fund, administered by the American Chemical Society. (Received, 26th November 1974; Corn. 1437.) 0. Hammerick and V. D. Parker, J.C.S. Chem. Comm., 1974, 245. N. Weinberg, 'Technique of Electroorganic Synthesis, Part 1,' Wiley, New York, 1974, p. 248. L. Eberson and K. Nyberg, Accounts Chem. Res., 1973, 6, 106. 4 L. L. Miller, V. R. Koch, T. Koenig and M. Tuttle, J. Amer. Chem. Soc., 1973, 95, 5075.",
year = "1975",
month = jan,
day = "1",
doi = "10.1039/C39750000262",
language = "English",
pages = "262--263",
journal = "Chemical Communications",
issn = "0022-4936",
publisher = "Royal Society of Chemistry",
number = "7",
}