Improved alumina transparency achieved by high-pressure spark plasma sintering of commercial powder

Barak Ratzker, Avital Wagner, Sergey Kalabukhov, Nachum Frage

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

Depending on starting powder and sintering conditions, alumina with extremely small grains and low residual porosity can be highly transparent. Combined with its excellent mechanical, thermal and chemical properties, transparent alumina is a promising material for a wide range of optical applications. In the present study, highly transparent alumina was fabricated by single-step high-pressure spark plasma sintering (HP-SPS) using raw commercial pure powder. The microstructure of the sintered alumina consists of fine grains with average size of ~170 nm and extremely fine residual porosity. The measured real in-line transmittance (RIT) was 72.6% at a wavelength of 640 nm, close to the calculated theoretical value (74.9%). The difference between theoretical and measured RIT was attributed to scattering by fine residual pores. This conclusion was supported by porosity analysis, and RIT calculations suggest that the porosity volume fraction is about 0.005%. The combination of fine grain size and high level of transparency could be suitable for potential advanced alumina-based laser materials.

Original languageEnglish
Pages (from-to)21794-21799
Number of pages6
JournalCeramics International
Volume46
Issue number13
DOIs
StatePublished - 1 Sep 2020

Keywords

  • Alumina (AlO)
  • Grain size
  • High-pressure spark plasma sintering
  • Porosity
  • Transparent ceramic

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Process Chemistry and Technology
  • Surfaces, Coatings and Films
  • Materials Chemistry

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