Inelastic neutron scattering band-shapes of mixed-valence molecular crystals

S. I. Klokishner; A. V. Palii; B. S. Tsukerblat

doi:10.1016/0038-1098(89)90554-1

Inelastic neutron scattering band-shapes of mixed-valence molecular crystals

S. I. Klokishner, A. V. Palii, B. S. Tsukerblat

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The electron-vibrational bands of neutron scattering by mixed valence(MV) molecular crystals containing clusters of transition metal ions in different states of oxidation as the structural units of lattice are considered. The neutron scattering band shape calculation in different phase states is performed in the semiclassical limit for crystals consisting of trielectronic clusters of transition metals of the type of d¹ - d^R. The shape of neutron scattering bands closely depends on the double and Heisenberg-type exchange parameters and the temperature dependence of the average dipole moment playing the role of the order parameter. The temperature dependence of the band shape brings the information about the parameters of vibronic interaction and charge ordering.

Original language	English
Pages (from-to)	879-883
Number of pages	5
Journal	Solid State Communications
Volume	71
Issue number	11
DOIs	https://doi.org/10.1016/0038-1098(89)90554-1
State	Published - 1 Jan 1989
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics
Materials Chemistry

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10.1016/0038-1098(89)90554-1

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title = "Inelastic neutron scattering band-shapes of mixed-valence molecular crystals",

abstract = "The electron-vibrational bands of neutron scattering by mixed valence(MV) molecular crystals containing clusters of transition metal ions in different states of oxidation as the structural units of lattice are considered. The neutron scattering band shape calculation in different phase states is performed in the semiclassical limit for crystals consisting of trielectronic clusters of transition metals of the type of d1 - dR. The shape of neutron scattering bands closely depends on the double and Heisenberg-type exchange parameters and the temperature dependence of the average dipole moment playing the role of the order parameter. The temperature dependence of the band shape brings the information about the parameters of vibronic interaction and charge ordering.",

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year = "1989",

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AU - Klokishner, S. I.

AU - Palii, A. V.

AU - Tsukerblat, B. S.

PY - 1989/1/1

Y1 - 1989/1/1

N2 - The electron-vibrational bands of neutron scattering by mixed valence(MV) molecular crystals containing clusters of transition metal ions in different states of oxidation as the structural units of lattice are considered. The neutron scattering band shape calculation in different phase states is performed in the semiclassical limit for crystals consisting of trielectronic clusters of transition metals of the type of d1 - dR. The shape of neutron scattering bands closely depends on the double and Heisenberg-type exchange parameters and the temperature dependence of the average dipole moment playing the role of the order parameter. The temperature dependence of the band shape brings the information about the parameters of vibronic interaction and charge ordering.

AB - The electron-vibrational bands of neutron scattering by mixed valence(MV) molecular crystals containing clusters of transition metal ions in different states of oxidation as the structural units of lattice are considered. The neutron scattering band shape calculation in different phase states is performed in the semiclassical limit for crystals consisting of trielectronic clusters of transition metals of the type of d1 - dR. The shape of neutron scattering bands closely depends on the double and Heisenberg-type exchange parameters and the temperature dependence of the average dipole moment playing the role of the order parameter. The temperature dependence of the band shape brings the information about the parameters of vibronic interaction and charge ordering.

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JO - Solid State Communications

JF - Solid State Communications

IS - 11

ER -

Inelastic neutron scattering band-shapes of mixed-valence molecular crystals

Abstract

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