Influence of Interactions in Solutions on the Solid Phase Formation in Ternary Water-Salt Systems

M. Yu Skripkin; L. V. Chernykh; O. N. Pestova; V. E. Baranauskaite; K. A. Burkov; I. V. Zamyatin; L. V. Stepakova; I. M. Gusev; A. O. Gorbunov; N. A. Bogachev; G. L. Starova

doi:10.1134/S1070363219060033

Influence of Interactions in Solutions on the Solid Phase Formation in Ternary Water-Salt Systems

M. Yu Skripkin, L. V. Chernykh, O. N. Pestova, V. E. Baranauskaite, K. A. Burkov, I. V. Zamyatin, L. V. Stepakova, I. M. Gusev, A. O. Gorbunov, N. A. Bogachev, G. L. Starova

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The influence of ionic interactions in ternary aqueous and aqueous-organic solutions of metal halides on the structure of the solid phases in equilibrium with the solutions is analyzed. An original classification of double and complex salts, reflecting the peculiarities of their structure, is given. The conditions for the formation of various types of these compounds are determined. The factors that determine the preservation of the metal ion surrounding during the solution-solid phase transition are revealed.

Original language	English
Pages (from-to)	1085-1101
Number of pages	17
Journal	Russian Journal of General Chemistry
Volume	89
Issue number	6
DOIs	https://doi.org/10.1134/S1070363219060033
State	Published - 1 Jun 2019
Externally published	Yes

Keywords

aqueous and water-organic solutions
complex salts
crystalline solvates
double salts
metal halides

ASJC Scopus subject areas

General Chemistry

Access to Document

10.1134/S1070363219060033

Cite this

Skripkin, M. Y., Chernykh, L. V., Pestova, O. N., Baranauskaite, V. E., Burkov, K. A., Zamyatin, I. V., Stepakova, L. V., Gusev, I. M., Gorbunov, A. O., Bogachev, N. A., & Starova, G. L. (2019). Influence of Interactions in Solutions on the Solid Phase Formation in Ternary Water-Salt Systems. Russian Journal of General Chemistry, 89(6), 1085-1101. https://doi.org/10.1134/S1070363219060033

@article{98ade8fed42145e8bf9580a012b2c386,

title = "Influence of Interactions in Solutions on the Solid Phase Formation in Ternary Water-Salt Systems",

abstract = "The influence of ionic interactions in ternary aqueous and aqueous-organic solutions of metal halides on the structure of the solid phases in equilibrium with the solutions is analyzed. An original classification of double and complex salts, reflecting the peculiarities of their structure, is given. The conditions for the formation of various types of these compounds are determined. The factors that determine the preservation of the metal ion surrounding during the solution-solid phase transition are revealed.",

keywords = "aqueous and water-organic solutions, complex salts, crystalline solvates, double salts, metal halides",

author = "Skripkin, {M. Yu} and Chernykh, {L. V.} and Pestova, {O. N.} and Baranauskaite, {V. E.} and Burkov, {K. A.} and Zamyatin, {I. V.} and Stepakova, {L. V.} and Gusev, {I. M.} and Gorbunov, {A. O.} and Bogachev, {N. A.} and Starova, {G. L.}",

note = "Publisher Copyright: {\textcopyright} 2019, Pleiades Publishing, Ltd.",

year = "2019",

month = jun,

day = "1",

doi = "10.1134/S1070363219060033",

language = "English",

volume = "89",

pages = "1085--1101",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "Pleiades Publishing",

number = "6",

}

Skripkin, MY, Chernykh, LV, Pestova, ON, Baranauskaite, VE, Burkov, KA, Zamyatin, IV, Stepakova, LV, Gusev, IM, Gorbunov, AO, Bogachev, NA & Starova, GL 2019, 'Influence of Interactions in Solutions on the Solid Phase Formation in Ternary Water-Salt Systems', Russian Journal of General Chemistry, vol. 89, no. 6, pp. 1085-1101. https://doi.org/10.1134/S1070363219060033

TY - JOUR

T1 - Influence of Interactions in Solutions on the Solid Phase Formation in Ternary Water-Salt Systems

AU - Skripkin, M. Yu

AU - Chernykh, L. V.

AU - Pestova, O. N.

AU - Baranauskaite, V. E.

AU - Burkov, K. A.

AU - Zamyatin, I. V.

AU - Stepakova, L. V.

AU - Gusev, I. M.

AU - Gorbunov, A. O.

AU - Bogachev, N. A.

AU - Starova, G. L.

PY - 2019/6/1

Y1 - 2019/6/1

N2 - The influence of ionic interactions in ternary aqueous and aqueous-organic solutions of metal halides on the structure of the solid phases in equilibrium with the solutions is analyzed. An original classification of double and complex salts, reflecting the peculiarities of their structure, is given. The conditions for the formation of various types of these compounds are determined. The factors that determine the preservation of the metal ion surrounding during the solution-solid phase transition are revealed.

AB - The influence of ionic interactions in ternary aqueous and aqueous-organic solutions of metal halides on the structure of the solid phases in equilibrium with the solutions is analyzed. An original classification of double and complex salts, reflecting the peculiarities of their structure, is given. The conditions for the formation of various types of these compounds are determined. The factors that determine the preservation of the metal ion surrounding during the solution-solid phase transition are revealed.

KW - aqueous and water-organic solutions

KW - complex salts

KW - crystalline solvates

KW - double salts

KW - metal halides

UR - http://www.scopus.com/inward/record.url?scp=85068641832&partnerID=8YFLogxK

U2 - 10.1134/S1070363219060033

DO - 10.1134/S1070363219060033

M3 - Article

AN - SCOPUS:85068641832

SN - 1070-3632

VL - 89

SP - 1085

EP - 1101

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

IS - 6

ER -

Influence of Interactions in Solutions on the Solid Phase Formation in Ternary Water-Salt Systems

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this