Influence of Ion Exchanger and Diluent Structure on Uranyl Ion Selective Electrode Response

Ilia Goldberg; Dan Meyerstein

doi:10.1021/ac50063a027

Influence of Ion Exchanger and Diluent Structure on Uranyl Ion Selective Electrode Response

Ilia Goldberg
, Dan Meyerstein

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

33 Scopus citations

Abstract

A series of uranyl complexes were tested as the active substance In the membranes of uranyl Ion selective electrodes, ISEs. Complexes with phosphites as ligands, ion exchangers, give better electrodes than those with phosphates and phosphonates. This observation seems to be related to the fact that phosphites are weaker ligands and therefore more labile ligands for uranyl. A simple technique for the preparation of PVC-based membranes for ISEs is described.

Original language	English
Pages (from-to)	2105-2108
Number of pages	4
Journal	Analytical Chemistry
Volume	52
Issue number	13
DOIs	https://doi.org/10.1021/ac50063a027
State	Published - 1 Nov 1980

ASJC Scopus subject areas

Analytical Chemistry

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title = "Influence of Ion Exchanger and Diluent Structure on Uranyl Ion Selective Electrode Response",

abstract = "A series of uranyl complexes were tested as the active substance In the membranes of uranyl Ion selective electrodes, ISEs. Complexes with phosphites as ligands, ion exchangers, give better electrodes than those with phosphates and phosphonates. This observation seems to be related to the fact that phosphites are weaker ligands and therefore more labile ligands for uranyl. A simple technique for the preparation of PVC-based membranes for ISEs is described.",

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AU - Goldberg, Ilia

AU - Meyerstein, Dan

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N2 - A series of uranyl complexes were tested as the active substance In the membranes of uranyl Ion selective electrodes, ISEs. Complexes with phosphites as ligands, ion exchangers, give better electrodes than those with phosphates and phosphonates. This observation seems to be related to the fact that phosphites are weaker ligands and therefore more labile ligands for uranyl. A simple technique for the preparation of PVC-based membranes for ISEs is described.

AB - A series of uranyl complexes were tested as the active substance In the membranes of uranyl Ion selective electrodes, ISEs. Complexes with phosphites as ligands, ion exchangers, give better electrodes than those with phosphates and phosphonates. This observation seems to be related to the fact that phosphites are weaker ligands and therefore more labile ligands for uranyl. A simple technique for the preparation of PVC-based membranes for ISEs is described.

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DO - 10.1021/ac50063a027

M3 - Article

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SN - 0003-2700

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JO - Analytical Chemistry

JF - Analytical Chemistry

IS - 13

ER -

Influence of Ion Exchanger and Diluent Structure on Uranyl Ion Selective Electrode Response

Abstract

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