Influence of the La0.2Sr0.7Ti0.95Ni0.05O3 (LSTN) Synthesis Method on SOFC Anode Performance

Moran Dahan, Ludmila Fadeev, Hagay Hayun, Michael Gozin, Yaniv Gelbstein, Brian A. Rosen

Research output: Contribution to journalArticlepeer-review


Solid oxide fuel cells are characterized by a high efficiency for converting chemical energy into electricity and fuel flexibility. This research work focuses on developing durable and efficient anodes for solid oxide fuel cells (SOFCs) based on exsolving nickel from the perovskite structure. A-site-deficient La- and Ni-doped strontium titanates (La0.2Sr0.7Ti0.95Ni0.05O3−δ, LSTN) were synthesized using four different techniques and mixed with Ce0.8Gd0.2O2−δ (GDC) to form the SOFC anode. The synthesis routes of interest for comparison included solid-state, sol-gel, hydrothermal, and co-precipitation methods. LSTN powders were characterized via XRD, SEM, TPR, BET and XPS. In situ XRD during reduction was measured and the reduced powders were analyzed using TEM. The impact of synthesis route on SOFC performance was investigated. All samples were highly durable when kept at 0.5 V for 48 h at 800 °C with H2 fuel. Interestingly, the best performance was observed for the cell with the LSTN anode prepared via co-precipitation, while the conventional solid-state synthesis method only achieved the second-best results.

Original languageEnglish
Article number79
Issue number1
StatePublished - 1 Jan 2024


  • anode
  • co-precipitation
  • combustion
  • hydrothermal
  • perovskite
  • solid oxide fuel cell

ASJC Scopus subject areas

  • Catalysis
  • General Environmental Science
  • Physical and Theoretical Chemistry


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