Instabilities across the isotropic conductivity point in a nematic phenyl benzoate under AC driving

Pramoda Kumar, Shivaram N. Patil, Uma S. Hiremath, K. S. Krishnamurthy

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

We characterize the sequence of bifurcations generated by ac fields in a nematic layer held between unidirectionally rubbed ITO electrodes. The material, which possesses a negative dielectric anisotropy εa and an inversion temperature for electrical conductivity anisotropy σa, exhibits a monostable tilted alignment near TIN, the isotropic-nematic point. On cooling, an anchoring transition to the homeotropic configuration occurs close to the underlying smectic phase. The field experiments are performed for (i) negative σa and homeotropic alignment, and (ii) weakly positive σa and nearly homeotropic alignment. Under ac driving, the Freedericksz transition is followed by bifurcation into various patterned states. Among them are the striped states that seem to belong to the dielectric regime and localized hybrid instabilities. Very significantly, the patterned instabilities are not excited by dc fields, indicating their possible gradient flexoelectric origin. The Can-Helfrich mechanism-based theories that take account of flexoelectric terms can explain the observed electroconvective effects only in part.

Original languageEnglish
Pages (from-to)8792-8800
Number of pages9
JournalJournal of Physical Chemistry B
Volume111
Issue number30
DOIs
StatePublished - 2 Aug 2007
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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