Interaction of thermal acylacetylenes with thiosemicarbazide and 4-methyl- and 4-phenylthiosemicarbazides

T. E. Glotova; A. S. Nakhmanovich; L. S. Romanenko; M. V. Sigalov

doi:10.1007/BF00864342

Interaction of thermal acylacetylenes with thiosemicarbazide and 4-methyl- and 4-phenylthiosemicarbazides

T. E. Glotova, A. S. Nakhmanovich, L. S. Romanenko, M. V. Sigalov

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

By the reaction of thiosemicarbazide and 4-methyl- and 4-phenylthiosemicarbazides with terminal α-acetylenic ketones, depending on the conditions, thiosemicarbazones of acylacetic aldehyde, 1,1-bis(acylvinyl)thiosemicarbazides,and5-phenylamino-2-acylmethyl-3-acylvinyl-1,3,4-thiadiazolinesareobtained. Ring-chain tautomerism of the 1,1-bis(acylvinyl)thiosemicarbazides has been investigated.

Original language	English
Pages (from-to)	1435-1440
Number of pages	6
Journal	Russian Chemical Bulletin
Volume	41
Issue number	8
DOIs	https://doi.org/10.1007/BF00864342
State	Published - 1 Aug 1992

Keywords

1,1-bis(acylvinyl)thiosemicarbazides
4-methylthiosemicarbazide
4-phenylthiosemicarbazide
5-amino(phenylamino)-2-acylmethyl-3-acylvinyl-1,3,4-thiadiazolines
acylacetylenes
thiosemicarbazide
thiosemicarbazones of acylacetic aldehyde

ASJC Scopus subject areas

General Chemistry

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10.1007/BF00864342

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title = "Interaction of thermal acylacetylenes with thiosemicarbazide and 4-methyl- and 4-phenylthiosemicarbazides",

abstract = "By the reaction of thiosemicarbazide and 4-methyl- and 4-phenylthiosemicarbazides with terminal α-acetylenic ketones, depending on the conditions, thiosemicarbazones of acylacetic aldehyde, 1,1-bis(acylvinyl)thiosemicarbazides,and5-phenylamino-2-acylmethyl-3-acylvinyl-1,3,4-thiadiazolinesareobtained. Ring-chain tautomerism of the 1,1-bis(acylvinyl)thiosemicarbazides has been investigated.",

keywords = "1,1-bis(acylvinyl)thiosemicarbazides, 4-methylthiosemicarbazide, 4-phenylthiosemicarbazide, 5-amino(phenylamino)-2-acylmethyl-3-acylvinyl-1,3,4-thiadiazolines, acylacetylenes, thiosemicarbazide, thiosemicarbazones of acylacetic aldehyde",

author = "Glotova, {T. E.} and Nakhmanovich, {A. S.} and Romanenko, {L. S.} and Sigalov, {M. V.}",

year = "1992",

month = aug,

day = "1",

doi = "10.1007/BF00864342",

language = "English",

volume = "41",

pages = "1435--1440",

journal = "Russian Chemical Bulletin",

issn = "1063-5211",

publisher = "Springer New York",

number = "8",

}

TY - JOUR

T1 - Interaction of thermal acylacetylenes with thiosemicarbazide and 4-methyl- and 4-phenylthiosemicarbazides

AU - Glotova, T. E.

AU - Nakhmanovich, A. S.

AU - Romanenko, L. S.

AU - Sigalov, M. V.

PY - 1992/8/1

Y1 - 1992/8/1

N2 - By the reaction of thiosemicarbazide and 4-methyl- and 4-phenylthiosemicarbazides with terminal α-acetylenic ketones, depending on the conditions, thiosemicarbazones of acylacetic aldehyde, 1,1-bis(acylvinyl)thiosemicarbazides,and5-phenylamino-2-acylmethyl-3-acylvinyl-1,3,4-thiadiazolinesareobtained. Ring-chain tautomerism of the 1,1-bis(acylvinyl)thiosemicarbazides has been investigated.

AB - By the reaction of thiosemicarbazide and 4-methyl- and 4-phenylthiosemicarbazides with terminal α-acetylenic ketones, depending on the conditions, thiosemicarbazones of acylacetic aldehyde, 1,1-bis(acylvinyl)thiosemicarbazides,and5-phenylamino-2-acylmethyl-3-acylvinyl-1,3,4-thiadiazolinesareobtained. Ring-chain tautomerism of the 1,1-bis(acylvinyl)thiosemicarbazides has been investigated.

KW - 1,1-bis(acylvinyl)thiosemicarbazides

KW - 4-methylthiosemicarbazide

KW - 4-phenylthiosemicarbazide

KW - 5-amino(phenylamino)-2-acylmethyl-3-acylvinyl-1,3,4-thiadiazolines

KW - acylacetylenes

KW - thiosemicarbazide

KW - thiosemicarbazones of acylacetic aldehyde

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U2 - 10.1007/BF00864342

DO - 10.1007/BF00864342

M3 - Article

AN - SCOPUS:34249832886

SN - 1063-5211

VL - 41

SP - 1435

EP - 1440

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 8

ER -

Interaction of thermal acylacetylenes with thiosemicarbazide and 4-methyl- and 4-phenylthiosemicarbazides

Abstract

Keywords

ASJC Scopus subject areas

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